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158 CHAPTER 10. FERMI LIQUID THEORY<br />

10.4.4 Quasiparticles detected in de Haas-van Alphen experiments<br />

Direct evidence for the existence <strong>of</strong> a heavy Fermi liquid state has come from the observation <strong>of</strong><br />

quantum oscillations (see Lent term part) in a number <strong>of</strong> heavy fermion materials. Fig. 10.11<br />

shows one <strong>of</strong> the clearest examples, UPt 3 . The volume enclosed by the Fermi surface is a very<br />

stringent criterion, which can be used to decide between the heavy Fermi liquid scenario – in<br />

which the f-electrons contribute to the Fermi surface – and local moment models. Moreover,<br />

the temperature dependence <strong>of</strong> the signal observed in quantum oscillation measurements can<br />

be used to determine the effective mass <strong>of</strong> the quasiparticles. This can be compared against the<br />

measured heat capacity. Where these comparisons were possible, such as in UPt 3 , the measured<br />

heat capacity was consistent with what would be expected from the measured effective masses.<br />

10.4.5 Heavy fermions, summary:<br />

• Many intermetallic compounds containing elements with partially filled 4f (Ce, Yb) or 5f<br />

(U) orbitals show heavy fermion behaviour.<br />

• Their low temperature properties are consistent with Fermi liquid theory, if we assume<br />

very high effective carrier masses.<br />

• What is the role <strong>of</strong> electrons in partially filled f-orbitals Do they behave like local<br />

moments or like conduction electrons Where quantum oscillation studies have been<br />

successful, they indicate that at low temperature the electrons contribute to the Fermi<br />

surface, like in a normal metal. At high temperature, on the other hand, they behave like<br />

local moments.<br />

• Because g(E F ) is so high in these materials, they tend to order magnetically or even<br />

become superconducting. There are many different ordered low temperature states in<br />

these metals, some simple, some very exotic.<br />

• There is an increasing number <strong>of</strong> materials (e.g. YbRh 2 Si 2 ), which do not follow Fermi<br />

liquid theory at low T . Are they ’non-Fermi’ liquids Do the f-electrons remain as local<br />

moments down to absolute 0 in this case, not contributing to the Fermi surface This is<br />

being investigated at the moment.

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