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46 CHAPTER 3. FROM ATOMS TO SOLIDS<br />

(3.19) defines a plane constructed perpendicular to the vector G and intersecting this vector<br />

at its midpoint. The set <strong>of</strong> all such planes defines those incident wavevectors that satisfy the<br />

conditions for diffraction (see Fig. 3.9).<br />

Figure 3.9: Ewald construction. The points are the reciprocal lattice <strong>of</strong> the crystal. k 0 is the<br />

incident wavevector, with the origin chosen so that it terminates on a reciprocal lattice point.<br />

A sphere <strong>of</strong> radius |k 0 | is drawn about the origin, and a diffracted beam will be formed if this<br />

sphere intersects any other point in the reciprocal lattice. The angle θ is the Bragg angle <strong>of</strong><br />

(3.21)<br />

This condition is familiar as Bragg’s Law. The condition (3.19) may also be written as<br />

2π<br />

λ sin θ = π d<br />

(3.20)<br />

where λ = 2π/k, θ is the angle between the incident beam and the crystal planes perpendicular<br />

to G, and d is the separation between the plane and the origin.

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