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82 CHAPTER 5. BANDSTRUCTURE OF REAL MATERIALS<br />
Figure 5.9: Band energy E(k) (solid line) and group velocity v(k) dashed line in a simple<br />
1D band. A wavepacket progressing its crystal momentum according to (5.17) accelerates as k<br />
increases from zero, and then slows and reverses direction as k approaches the zone boundary.<br />
so that the wave packet <strong>of</strong> electrons oscillates up and down the energy surface. It we start<br />
from the minimum <strong>of</strong> the band, then the group velocity grows linearly in time as for a free<br />
electron accelerating (though with a mass different from the free electron mass). However, on<br />
approaching the zone boundary, the group velocity slows - the acceleration <strong>of</strong> the particle is<br />
opposite to the applied force. What is actually happening is buried within the semiclassical<br />
model via the dispersion ɛ(k): as the wavepacket approaches the Brillouin zone boundary, real<br />
momentum (not crystal momentum k) is transferred to the lattice, so that on reaching the zone<br />
boundary the particle is Bragg-reflected.<br />
Thus a DC electric field may be used - in principle - to generate an AC electrical current. All<br />
attempts to observe these Bloch oscillations in conventional solids has so far failed. The reason<br />
is that in practice it is impossible to have wavepackets reach such large values <strong>of</strong> momentum as<br />
π/a due to scattering from impurities and phonons in the solid. We will incorporate scattering<br />
processes in the theory in a moment.<br />
It turns out however, that one can make artificial periodic potentials in a semiconductor<br />
superlattice. The details <strong>of</strong> this process will be discussed later, but for our purposes the net<br />
effect is to produce a square well potential that is periodic with a periodicity that can be much<br />
longer than the atom spacing. The corresponding momentum at the zone boundary is now<br />
much smaller, so the wavepacket does not have to be excited to such high velocities. The<br />
signature <strong>of</strong> the Bloch oscillations is microwave radiation produced by the oscillating charge -<br />
at a frequency that is proportional to the DC electrical field.