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Contents<br />

1 Classical models for electrons in solids 9<br />

1.1 Lorentz oscillator model . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9<br />

1.2 Drude model . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13<br />

2 Sommerfeld theory 23<br />

2.1 The problems with Drude theory . . . . . . . . . . . . . . . . . . . . . . . . . . 23<br />

2.2 Free electron gas in three-dimensions . . . . . . . . . . . . . . . . . . . . . . . . 24<br />

2.3 Fermi surface, and density <strong>of</strong> states . . . . . . . . . . . . . . . . . . . . . . . . . 25<br />

2.4 Thermal properties <strong>of</strong> the electron gas . . . . . . . . . . . . . . . . . . . . . . . 26<br />

2.5 Screening and Thomas-Fermi theory . . . . . . . . . . . . . . . . . . . . . . . . 27<br />

3 From atoms to solids 33<br />

3.1 The binding <strong>of</strong> crystals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33<br />

3.2 Complex matter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37<br />

3.3 The description <strong>of</strong> periodic solids . . . . . . . . . . . . . . . . . . . . . . . . . . 42<br />

3.4 The reciprocal lattice and diffraction . . . . . . . . . . . . . . . . . . . . . . . . 44<br />

3.5 Diffraction conditions and Brillouin zones . . . . . . . . . . . . . . . . . . . . . . 45<br />

3.6 Lattice dynamics and phonons . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48<br />

3.7 Lattice specific heat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52<br />

4 Electronic structure 55<br />

4.1 Schrödinger equation in a periodic potential . . . . . . . . . . . . . . . . . . . . 55<br />

4.2 Bloch’s theorem from discrete translational symmetry . . . . . . . . . . . . . . . 57<br />

4.3 Nearly free electron theory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60<br />

4.4 Tight binding: Linear combination <strong>of</strong> atomic orbitals . . . . . . . . . . . . . . . 65<br />

4.5 Pseudopotentials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71<br />

5 Bandstructure <strong>of</strong> real materials 73<br />

3

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