rok 2006 - Fakulta chemickej a potravinárskej technológie ...

Organic Chemistry Laboratory 0/0/4 Lásiková, Wiesenganger
4. semester (Bc) (Pt) Organic Chemistry 1/1/0 Špirková
Organic Chemistry Laboratory 0/0/4 Stankovský, Winklerová
5. semester (Bc) Chemical Information 1/1/0 Zálupský,
6. semester (Bc) Chemical Specialities 2/2/0 Mravec, Štibrányi
Semestral Project 0/0/4 Berkeš, Fišera, Koreňová, Stankovský, Šafář
1. semester (MSc) Organometallic Compounds 1/1/0 Gracza
Mechanisms of Organic
Reactions I
3/1/0 Fišera
Bioorganic Chemistry 2/0/0 Berkeš
Laboratory Project I 0/0/10 Koreňová, Berkeš
1. semester (MSc) Organic Chemistry III 1/1/0 Považanec
2. semester (MSc) Organic Synthesis 2/1/0 Floch
Asymmetric Synthesis 2/1/0 Gracza
Stereochemistry 0/2/0 Štibrányi
Spectroscopic Methods in the
Control of Technology
2/2/0 Milata, Segľa
2. semester (MSc) Laboratory Project II 0/0/6 Šafař, Štibrányi
Training at Industrial
Fišera, Gracza, Lásiková, Marchalín, Milata,
15 d
Production Floor
Považanec, Szolcsányi
3. semester (MSc)
Mechanisms of Organic
Reactions II
1/1/0 Marchalín
Applied Organic Synthesis 1/1/0 Považanec
Physical Organic Chemistry I 0/2/0 Milata
Chemistry of Heterocyclic
Compounds
2/0/0 Stankovský
Chemistry of Natural
Substances and Drugs
2/0/0 Berkeš
Chemical Information
Systems
2/0/0 Zálupský
3. semester (MSc) Laboratory Project 0/0/10
Fišera, Gracza, Lásiková, Marchalín, Milata,
Považanec, Szolcsányi
4. semester (MSc) Diploma Seminar Považanec
Diploma Thesis Project
Fišera, Milata, Štibrányi, Végh
C. Doctoral Study:
1. semester (PhD) Advanced Organic Chemistry 2/0/0 Gracza
1. semester (PhD) Advanced Stereochemistry 2/0/0 Fišera
2. semester (PhD) Structure Reactivity Relationship 2/0/0 Marchalín
3. semester (PhD) Advanced Organic Chemistry 2/0/0 Milata
3. semester (PhD) Chemistry of Heterocyclic Compounds 2/0/0 Végh
IV. CURRENT RESEARCH PROJECTS
VEGA project No 1/3549/2006 Asymmetric and Stereoselective Reactions. Dipolar
Cycloadditions, Sm(II)-Induced Additions, Cyclizations and Oxycarbonylations in the Total
Syntheses of Natural Products and Its Analogues (Lubor Fišera)
The Sm(II) induced diastereoselective reductive coupling of sugar derived nitrones with ethyl acrylate will provide
access to a variety of functionalized amino acids directly, or to amino acids as constituents of small peptides. The
stereoselective synthesis of optically active polysubstituted pyrrolidin-2-ones and piperidine-2-ones from chiral
amino acids which are promising precursors for the synthesis of several pyrrolizidine, pyrrolidine, indolizidine and
piperidine alkaloids. The synthesis of non-proteinogenic amino acids derived nitrones, isoxazolidinyl nucleosides,
spironucleosides and azanucleosides. The study of the effect of Lewis acids to influence diastereoselectivity of
nitrone cycloaddition reactions.
Asymmetric palladium(II)-catalyzed oxy-/aminocarbonylation and oxa-/aminobicyclization of unsaturated polyols
and aminopolyols. Catalyst design using the calculation of the model for transition state. Correlation of
enantioselectivity with calculated models of the transition states for prediction of the reaction stereoselectivity and
stereochemistry of the products. The application of these reactions as the asymmetric key-steps in the total
syntheses of natural compounds.
Project duration: from 01.01.2006 to 31.12.2008
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