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MVTS Project No NEM/Slov/DAAD/Darm05 Magneto-structural relationships for novel substances and materials (Roman Boča). New type of the magnetostructural correlation in mononuclear complexes has been outlined; magnetic anisotropy parameter D (that is the axial zero-field splitting) correlates with the structural distortion given by the departure of the chromophore from the octahedral symmetry. This knowledge could be of a key importance for a rational design of single-molecule magnets and a fine tuning of their properties. See: R. Ivaniková, R. Boča, L. Dlháň, H. Fuess, A. Mašlejová, V. Mrázová, I. Svoboda, J. Titiš: Polyhedron 25 (2006) 3261-3268. Heteroleptic nickel(II) complexes formed of N-donor bases, carboxylic acids, and water: Magnetostructural correlations Project duration: from 01. 01. 2005 to 31. 12. 2007 MVTS Project No NEM/Slov/DFG/CH Molecular Electronic Multistability (Roman Boča). Spin crossover phenomenon was studied by several experimental techniques: SQUID magnetometry and Moessbauer spectroscopy on novel polynuclear substances. The prepared iron(II) and Fe(III) complexes show a temperature-induced spin crossover. In the case of dinuclear and polynuclear complexes a stepwise process is relevant (multistep spin crossover). Project duration: from 01. 01. 2002 to 31. 12. 2007 APVT Project No 20-005204 Magnetostructural Correlations in Unconventional Magnetic Materials (Roman Boča). Polynuclear complexes have been sysnthesized and their magnetoactivity investigated in detail. By a simultaneous analysis of the temperature dependence of the magnetic susceptibility and a field dependence of the magnetization the key magnetic parameters have been withdrawn: the exchange coupling constant, the axial zero-field splitting parameter D and the magnetogyric ratio g for individual centers. See: a) C. G. Efthymiou, C. P. Raptopoulou, A. Terzis, R. Boča, M. Korabic, J. Mrozinski, .S. P. Perlepes, E. G. Bakalbassis: Eur. J. Inorg. Chem. (2006) 2236–2252. A Systematic Exploration of Nickel(II)/Acetate/Di-2-pyridyl Ketone Chemistry: Neutral and Cationic Tetranuclear Clusters, and a Novel Mononuclear Complex b) O. Atakol, R. Boča, I. Ercan, F. Ercan, H. Fuess, W. Haase, R. Herchel: Chem. Phys. Lett. 423 (2006) 192–196 Magnetic properties of trinuclear Ni-M-Ni complexes, M = Mn, Co and Ni Project duration: from 01. 08. 2005 to 31. 12. 2007 ECONET Project (France-Slovakia) Etude par méthode FORC du comportement hystérétique de solides moléculaires commutables (Roman Boča). Modeling of the hysteresis behaviour for spin crossover materials has been done. This leads to understadings of the solid-state cooperativeness that rules the switching from the low-spin to high-spin state and back. Project duration: from 01. 08. 2005 to 31. 12. 2006 DAAD Project (Germany-Slovakia) Magneto-structural correlations in molecular magnetism (Roman Boča). The project is focusing to the magneto-structural correlations in the inorganic materials based on the transition metal complexes. See: A. Mašlejová, R. Ivaniková, I. Svoboda, B. Papánková, L. Dlháň, D. Mikloš, H. Fuess, R. Boča: Polyhedron 25 (2006) 1823–1830. Structural characterization and magnetic properties of hexakis(imidazole)nickel(II) bis(formate), bis(chloracetate), bis(2-chloropropionate) and hexakis(1-methyl-imidazole)nickel(II) chloride dihydrate Project duration: from 01. 01. 2006 to 31. 12. 2007 30
STEFANIK Project (France-Slovakia) Modeling of the photoswitchable molecular magnetic materials (Roman Boča). Spin crossover systems exhibiting thermal hysteresis along with a thermochromic effect can be exploited as new systems for data-recording and displaying units. Photoswitchable magnetic molecular materials are applicable in a superfast data recording/reading process for a new generation of computers and other devices. Project duration: from 01. 01. 2006 to 31. 12. 2007 VEGA Project 1/2452/05 Novel Complexes of Bioligands: Synthesis, Structure, Properties and Applicatios (Milan Melník). Investigation of new metal complexes exhibiting controlled antiphlogistic and antituberculotic effects is an important task of contemporary bioinorganic chemistry. The project is focused on a complete research of the formation, structure, properties and practical applications of copper, iron, zinc and other metal complexes with non-steroid antiphlogistics (derivatives of salicylic and propionic acids, fenamates) and antituberculotics (derivatives of quinolons, nicotinic acid, nocotinamide, pyridylcarbinol and imidazole). The synthesized complexes will be studied as solids and in the solutions by x-ray diffraction of crystals and powders, spectral, magnetic, thermal, electrochemical and photochemical methods. Obtained characterization of the compounds will be compared and confronted with literature data in order to extract trends related to important biological aspects. A basic biological screening of the prepared complexes will be focused on cytotoxicity and its mechanisms. Conclusions about relation between the chemical structure and the cytotoxic activity will be formulated and applied to preparation of new substances. Project duration: from 01. 01. 2005 to 31. 12. 2007 APVT Project APVT-20-005504 Synthesis and investigation nonsteroidal antiflogistics based on copper(II) complexes (Milan Melník). The submitted project is aimed at studying conditions of preparation, electronic, vibrational and EPR spectra, molecular and crystal structures of solid Cu(II) complexes with ligands of therapeutical importance, such as derivatives of salicylic, propionic, fenamatic acids, andwith neutral ligands. In addition, an attention will be paid to solution properties of the complexes, particularly to their speciation. Biological screening will be performed. Redox behaviour of the complexes using electrochemical and photochemical methods will be investigated and compared to that of analogous iron complexes with structural and functional model compounds. Most of experimental work will be carried out at Department of Inorganic Chemistry. The results obtained will be published in CC journals and presented at conferences, or patented. Project duration: from 01. 01. 2005 to 31. 12. 2007 VI. COOPERATION A. Cooperation in Slovakia Institution Type of cooperation Responsible person Duration Pharmaceutical Faculty, Comenius University, Bratislava Medical Faculty, Comenius University, Bratislava Synthesis and spectral properties of Schiff base with Cu(II) complexes Cu(II) Schiff-base complexes as perspective antidotes Valent Aladár, Assoc. professor, Kalinčiakova 8, 832 32 Bratislava Čársky Jozef, professor, Sasinkova 10, 813 72 Bratislava 2002 - 2000 - B. International Cooperation Institution Type of cooperation Responsible person Duration Materials Science, University of Technology, Darmstadt, Germany Institute of Inorganic Chemistry, Johannes-Guttenberg- University, Mainz, Germany New Crystal, Molecular, Electronic and Magnetic Structures with Functional Properties Molecular Electronic Multistability Fuess Hartmut, professor, Petersenstrasse 23, 64287 Darmstadt, Germany Renz Franz, Dr., Staudinger Weg 9, D-55099 Mainz, Germany 1994 - 2002 - 31
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3.semester(MS) Laboratory M.Polakov
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stability of food enzymes, the inac
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Project duration: from 2006 to 2008
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VŠCHT Praha, ČR CIBA Spezialität
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Markoš Jozef Slovak Society of Che
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Jelemenský SACEC 2006, Durban, Uni
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[8] Katrlík, J., Mastihuba, V., Vo
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Conference Biocatalysis in the Food
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DEPARTMENT OF CHEMICAL PHYSICS Head
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The stability of polymers with sele
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D. Membership in International Orga
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Article in conference proceedings [
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DEPARTMENT OF CHEMICAL TECHNOLOGY O
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VI. COOPERATION A. Cooperation in S
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B. Graduate Theses (MS Degree) for
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3. semester (MSc) Risk Properties o
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Project duration: from 01.05.2006 t
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Institute of Chemical Technology, P
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Hutňan,M. Excursion on Biogas Stat
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[12] Derco, Ján, Dudáš, Jozef, J
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Optional 2. semester (MSc) Special
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Legéň Jaroslav Slovak Chemical So
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[19] Murárová, A., Podobeková, S
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DEPARTMENT OF FOOD SCIENCE AND TECH
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B. VEGA Project No 1/9133/02 Develo
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Institute of Food Research, Manches
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Schmidt, S. Sekretár, S. Zahradní
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[14] Hojerová, J.: Špecifiká koz
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o tenzidech detergentech, Lázne Bo
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B. Undergraduate Study: Technology
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VI. COOPERATION A. Cooperation in S
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VII. THESES AND DISSERTATIONS A. Gr
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DEPARTMENT OF INFORMATION ENGINEERI
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control. Developed algorithms, cont
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Control Engineering Laboratory, FEI
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F. Visits of Staff Members and Post
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[4] Bakošová, M., Baleja, J., Vas
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7. International Scientific-Technic
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5. semester (Bc) Technical English
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DEPARTMENT OF MANAGEMENT Head of De
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TENTO, Inc. Žilina Chemosvit, Inc.
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Name Organisation or Institution St
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VIII. PUBLICATIONS Book [1] Baran,
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[35] Špirko, D.: Globálne marketi
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IV. CURRENT RESEARCH PROJECTS Conju
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C. Membership in Domestic Organizat
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[10] Janiga, I., Mocák, J., Cisko,
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DEPARTMENT OF ORGANIC CHEMISTRY Hea
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APVV project LPP-0238-06 Asymmetric
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Slovak Academy of Sciences, Bratisl
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Lásiková Angelika Slovak Society
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Article in journal [1] Babjak, Mate
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DEPARTMENT OF ORGANIC TECHNOLOGY He
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project in the field of catalytic p
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Hronec M. SC ICT, Praha CR 28. - 29
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[19] Vlčko, Miroslav, Hronec, Mila
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Laboratory practice I 0/0/8 Daučí
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Hudec P. 17th International Congres
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[19] Klepáčová, Katarína, Mrave
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1. semester (MSc) Chemical Physics
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Value Chain (Peter Šimon) FP6 EU p
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C. Dissertations (PhD) Name Title o
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[52] Šimon, P., Illeková, E., Moj
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the thiphene-thiophene versus pheny
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VIII. PUBLICATIONS Book [1] Bobrík
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Production and Processing of Rubber
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Rubber Research Institute Matador,
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Urogiová E. German Rubber Conferen
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Slovenská konference POLYMERY 2006
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