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gas hydrate - CCOP

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Gas pr oduct i on r at e ml /min<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

0 20 40 60 80 100<br />

Ti me<br />

min<br />

Figure 8. Gas production rate by<br />

depressurization.<br />

<br />

Cumul at i ve <strong>gas</strong> pr oduced ml<br />

10000<br />

8000<br />

6000<br />

4000<br />

2000<br />

0<br />

0 20 40 60 80 100<br />

Ti me<br />

min<br />

Figure 9. Accumulated <strong>gas</strong> by<br />

depressurization.<br />

Figures 10 and 11 plot the water production rate and cumulative water produced with time.<br />

It can be revealed that:<br />

1) The start time for water produced lags behind than that of the <strong>gas</strong>. This is due to the<br />

fact that less free water exists in the experimental vessel after <strong>hydrate</strong> formation.<br />

2) After certain time, there is a water rate peak before a rapid decrease.<br />

3) The water produced keeps at a stable level until no water flows out. At this stage, the<br />

water produced is mainly due to <strong>hydrate</strong> dissociation.<br />

<br />

Wat er pr oduct i on r at e ml / mi n<br />

3. 5<br />

3<br />

2. 5<br />

2<br />

1. 5<br />

1<br />

0. 5<br />

0<br />

0 20 40 60 80 100<br />

Ti me<br />

min<br />

Figure 10. Water production rate by<br />

depressurization.<br />

40<br />

Cumul at i ve wat er pr oduced<br />

ml <br />

30<br />

20<br />

10<br />

0<br />

0 20 40 60 80 100<br />

Ti me<br />

min<br />

Figure 11. Accumulated water by<br />

depressurization.<br />

Figure 12 plots the temperature profile during the depressurization experiment. It can be<br />

revealed that the environmental temperature keeps constant, however the temperature profiles<br />

for other measuring points show similar trend, i.e., the temperature decreases first before<br />

increasing. This suggests that <strong>hydrate</strong> dissociation is an endothermic process.<br />

It can be concluded that depressurization is a good way for <strong>hydrate</strong> production in the current<br />

experimental conditions.<br />

72<br />

New Energy Resources in the <strong>CCOP</strong> Region - Gas Hydrates and Coalbed Methane

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