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halogen-specific detector for <strong>the</strong> analysis <strong>of</strong> halogenated volatileorganics including vinyl chloride in solid waste. Under <strong>the</strong> prescribedconditions for vinyl chloride, <strong>the</strong> method has a detection limit <strong>of</strong> 0.18ug/l. Precision and method accuracy were found to be directly related to<strong>the</strong> concentration <strong>of</strong> <strong>the</strong> parameter and essentially independent <strong>of</strong> <strong>the</strong>sample matrix. [USEPA; Test Methods for Evaluating Solid Waste SW-846(1986)]**PEER REVIEWED**EPA Method 8240. GC/MS for <strong>the</strong> determination <strong>of</strong> volatile organics. Thismethod can be used to quantify most volatile organic compounds includingvinyl chloride that have boiling points below 200 deg C and are insolubleor slightly soluble in water. The detection limit is not given. Precisionand method accuracy were found to be directly related to <strong>the</strong> concentration<strong>of</strong> <strong>the</strong> analyte and essentially independent <strong>of</strong> <strong>the</strong> sample matrix. [USEPA;Test Methods for Evaluating Solid Waste SW-846 (1986)]**PEER REVIEWED**EPA Method 601. Purge and Trap GC with electrolytic conductivity detectionfor <strong>the</strong> analysis <strong>of</strong> purgeable halocarbons including vinyl chloride inmunicipal and industrial discharges. Under <strong>the</strong> prescribed conditions, <strong>the</strong>method detection limit for vinyl chloride is 0.18 ug/l. The method isrecommended for use in <strong>the</strong> concentration range from <strong>the</strong> method detectionlimit to 1000 times that limit. Precision and method accuracy were foundto be directly related to <strong>the</strong> concentration <strong>of</strong> <strong>the</strong> parameter andessentially independent <strong>of</strong> <strong>the</strong> sample matrix. [40 CFR 136, App. A(7/1/90)]**PEER REVIEWED**EPA Method 624. Purge and Trap GC/MS for <strong>the</strong> analysis <strong>of</strong> purgeableorganics including vinyl chloride in <strong>the</strong> municipal and industrialdischarges. Under <strong>the</strong> prescribed conditions for vinyl chloride, <strong>the</strong> methoddetection limit is not given. Precision and method accuracy were found tobe directly related to <strong>the</strong> concentration <strong>of</strong> <strong>the</strong> parameter and essentiallyindependent <strong>of</strong> <strong>the</strong> sample matrix. [40 CFR 136, App. A (7/1/90)]**PEERREVIEWED**EPA Method 1624. Isotope Dilution Purge and Trap GC/MS. This method isapplicable for <strong>the</strong> determination <strong>of</strong> volatile organic compounds inmunicipal and industrial discharges. By adding a known amount <strong>of</strong> anisotopically labeled compound to every sample prior to purging, acorrection <strong>of</strong> recovery <strong>of</strong> <strong>the</strong> pollutant can be made. If isotopicallylabeled compounds are not available, an internal standard method is used.Under <strong>the</strong> prescribed conditions for both <strong>the</strong> isotopically labeled andunlabeled vinyl chloride <strong>the</strong> method has a minimum detection level <strong>of</strong> 50and 10 ug/l with no interferences present. [40 CFR 136, App. A(7/1/90)]**PEER REVIEWED**EPA Method 524.2. Purge and Trap GC/MS for <strong>the</strong> determination <strong>of</strong> volatilearomatic compounds in finished drinking water, raw source water, ordrinking water in any treatment stage. For vinyl chloride <strong>the</strong> method has adetection limit <strong>of</strong> 0.17 ug/l and a relative standard deviation <strong>of</strong> 6.7%with a wide bore capillary column, and a method detection limit <strong>of</strong> 0.04ug/l and a relative standard deviation <strong>of</strong> 0.2% with a narrow borecapillary column. [USEPA; Methods for <strong>the</strong> Determination <strong>of</strong> OrganicCompounds in Finished Drinking Water and Raw Source Water (1986)]**PEERREVIEWED**EPA Method 524.1. Purge and Trap GC/MS. The method is applicable for <strong>the</strong>determination <strong>of</strong> volatile organic compounds in water, finished drinking

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