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water, raw source water, or drinking water in any treatment stage. Forvinyl chloride the method has a detection limit of 0.31 ug/l and astandard deviation of 10.8%. [USEPA; Methods for the Determination ofOrganic Compounds in Finished Drinking Water and Raw Source Water(1986)]**PEER REVIEWED**EPA Method 502.2: Purge and Trap Capillary Column GC with Photoionizationand Electrolytic Conductivity Detectors in Series. The method isapplicable for the determination of volatile organic compounds in finisheddrinking water, raw source water, or drinking water in any treatmentstage. For vinyl chloride the method has a detection limit of 0.02 ug/l, apercent recovery of 109%, and a standard deviation of 5.4 using thephotoionization detector; and a method detection limit of 0.04 ug/l, apercent recovery of 95%, and a standard deviation of recovery of 5.6 usingthe electrolytic conductivity detector. [USEPA; Methods for theDetermination of Organic Compounds in Finished Drinking Water and RawSource Water (1986)]**PEER REVIEWED**EPA Method 502.1. Purge and Trap GC with a halogen-specific detector forthe determination of halogenated volatile compounds including vinylchloride in finished drinking water, raw source water, or drinking waterin any treatment stage. Under the prescribed conditions for vinylchloride, the method detection limit is 0.006 ug/l. [USEPA; Methods forthe Determination of Organic Compounds in Finished Drinking Water and RawSource Water (1986)]**PEER REVIEWED**EPA Method 8260. GC/MS for the determination of volatile organiccompounds. This method can be used to quantitate most volatile organiccompounds including vinyl chloride that have boiling points below 200 degC and are insoluble or slightly soluble in water. Under the prescribedconditions for vinyl chloride the method has a detection limit of 0.17ug/l, a percent recovery of 98%, and a percent relative standard deviationof 6.7% using a wide bore capillary column; and a detection limit of 0.04ug/l, a percent recovery of 104% and a percent relative standard deviationof 0.2% using a narrow bore capillary column. [USEPA; Test Methods forEvaluating Solid Waste SW-846 (1986)]**PEER REVIEWED**EPA Method 5030. Purge and Trap extraction procedure for the analysis ofvolatile organics. Such cmpds include low-molecular weight halogenatedhydrocarbons, aromatics, ketones, nitriles, acetates, acrylates, ethersand sulfides. An inert gas is bubbled through the solution at ambienttemperature, and the volatile components are efficiently transferred fromthe aqueous phase to the vapor phase. After purging is complete, thesorbent column is heated and backflushed with inert gas to desorb thecomponents onto a GC column. Water samples can be analyzed directly, whilepreparation is necessary for water-miscible liquids, solids, wastes andsoil/sediments. [USEPA; Test Methods for Evaluating Solid Waste SW-846(1986)]**PEER REVIEWED**EPA Method 5040. Protocol for Analysis of Sorbent Cartridges from VolatileOrganic Sampling Train. This method covers the determination of volatileprincipal organic hazardous constituents collected on Tenax andTenax/charcoal sorbent cartridges using a volatile organic sampling train,from wet stack gas effluents from hazardous waste incinerators. Thecontents of the sorbent cartidges are thermally desorbed, bubbled, andtrapped on an analytical adsorbent trap. The desired target detectionlimit of the analytical method is 0.1 ng/l. Interferences include
phthalate esters, detectable levels of volatile principal hazardousconstituents in blanks, and soap residue on the glassware. [USEPA; TestMethods for Evaluating Solid Waste SW-846 (1986)]**PEER REVIEWED**AOB Method VA-002-1. Volatile Organic Compounds (VOCs) by GC/MS Analysisof Tenax/CMS Cartridge and Summa Canister Samples. No detection limit.[USEPA; EMMI. EPA's Environmental Monitoring Methods Index. Version 1.1.PC# 4082. Rockville, MD: Government Institutes (1997)]**PEER REVIEWED**AOB Method VA-006-1. Volatile Organic Compounds (VOCs) in Ambient Air byDirect Portable GC/PID. No detection limit. [USEPA; EMMI. EPA'sEnvironmental Monitoring Methods Index. Version 1.1. PC# 4082. Rockville,MD: Government Institutes (1997)]**PEER REVIEWED**AOB Method VA-008-1. Volatile Organic Compounds (VOCs) in Ambient Air byPortable GC/PID with Direct Sampling via Pump and Sample Loop. Nodetection limit. [USEPA; EMMI. EPA's Environmental Monitoring MethodsIndex. Version 1.1. PC# 4082. Rockville, MD: Government Institutes(1997)]**PEER REVIEWED**APHA Method 6210-D. Volatile Organics in Water by Gas Chromatographic/Mass Spectrometric Purge and Trap Capillary-Column Technique. No detectionlimit [USEPA; EMMI. EPA's Environmental Monitoring Methods Index. Version1.1. PC# 4082. Rockville, MD: Government Institutes (1997)]**PEERREVIEWED**USEPA; EMMI. EPA's Environmental Monitoring Methods Index. Version 1.1.PC# 4082. Rockville, MD: Government Institutes (1997)] APHA Method 6230-D.Volatile Halocarbons in Water by Purge and Trap Capillary-Column GasChromatography. Detection limit = 0.05 ug/l. **PEER REVIEWED**OSW Method 5021. Volatile Organic Compounds in Soils and Other SolidMatrices Using Equilibrium Headspace Analysis. No detection limit. [USEPA;EMMI. EPA's Environmental Monitoring Methods Index. Version 1.1. PC# 4082.Rockville, MD: Government Institutes (1997)]**PEER REVIEWED**SAMPLING PROCEDURES:NIOSH Method 1007. Analyte: Vinyl chloride. Matrix: Air. Sampler: Solidsorbent tube (2 tandem tubes, each with 150 mg activated coconutcharcoal). Flow Rate: 0.05 l/min. Sample Size: 5 liters. Shipment:Separate primary and backup tubes and cap each. Sample Stability: 10 days@ 25 deg C. [U.S. Department of Health and Human Services, Public HealthService. Centers for Disease Control, National Institute for OccupationalSafety and Health. NIOSH Manual of Analytical Methods, 3rd ed. Volumes 1and 2 with 1985 supplement, and revisions. Washington, DC: U.S. GovernmentPrinting Office, February 1984.1007-1]**PEER REVIEWED**EPA Method 8010. For the analysis of solid waste, a representative sample(solid or liquid) is collected in a standard 40 ml glass screw-cap VOAvial equipped with a Teflon-faced silicone septum. Sample agitation, aswell as contamination of the sample with air, must be avoided. Two vialsare filled per sample location, then placed in separate plastic bags forshipment and storage. [USEPA; Test Methods for Evaluating Solid WasteSW-846 (1986)]**PEER REVIEWED**SPECIAL REFERENCES:
Page 1:
The following information was gener
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... ANOREXIA, ... ALLERGIC DERMATIT
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cancer. Many of the workers had bee
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personnel records of nine chemical
Page 11 and 12:
worker consumed more than a very lo
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(1): 37-45 (1991)]**PEER REVIEWED**
Page 15 and 16:
workers to the vinyl chloride monom
Page 17 and 18:
skin cancer could bear some relatio
Page 19 and 20:
N-5'-alkylpurine (AP) endonucleases
Page 21 and 22:
Agency for Research on Cancer, 1979
Page 23 and 24:
LIFE SUPPORT:oThis overview assumes
Page 25 and 26: exposure circumstance entails expos
Page 27 and 28: for carcinogenicity in human epidem
Page 29 and 30: Risk of Chemicals to Man. Geneva: W
Page 31 and 32: exposure groups did not differ from
Page 33 and 34: in vivo. [Barbin A; IARC 150: 303-1
Page 35 and 36: developed to localize the promutage
Page 37 and 38: WORKERS. THE VALUE OBTAINED WERE IN
Page 39 and 40: (2): 259 (1977)]**PEER REVIEWED**Af
Page 41 and 42: y 1 mg/cu m of either /cmpd/ separa
Page 43 and 44: (1980) as cited in USEPA; Health an
Page 45 and 46: (1975)]**PEER REVIEWED**ENVIRONMENT
Page 47 and 48: The Koc of vinyl chloride is estima
Page 49 and 50: REVIEWED**SEDIMENT/SOIL CONCENTRATI
Page 51 and 52: Fugitive emission sources; (3) Leak
Page 53 and 54: BOILING POINT:-13.3 deg C [Lide, D.
Page 55 and 56: Washington, D.C: U.S. Government Pr
Page 57 and 58: Reactivity: 2. 2= This degree inclu
Page 59 and 60: Vinyl chloride/ decomposes on burni
Page 61 and 62: available./ ... Safety pipettes sho
Page 63 and 64: Analytical procedures ... should be
Page 65 and 66: equipment. [Association of American
Page 67 and 68: done without undue risk. Use water
Page 69 and 70: Fishbein, R. A. Griesemer, A.B. Swa
Page 71 and 72: 673-6121; Production site: Geismar,
Page 73 and 74: 91% FOR POLYVINYL CHLORIDE [Kavaler
Page 75: halogen-specific detector for the a
Page 79 and 80: USEPA; Drinking water Criteria Docu
Page 81 and 82: ADMINISTRATIVE INFORMATION:HAZARDOU
Page 83: Field Update on 01/15/1990, 1 field
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