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Program Book - Master Brewers Association of the Americas

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P-177<br />

Enhancements to <strong>the</strong> flavor stability <strong>of</strong> beer through reaction<br />

rate improvements in oxygen scavenging crown liner<br />

compounds<br />

GREGORY POLLOCK (1), Thomas Kunz (2), Frank-Jurgen<br />

Methner (2)<br />

(1) Grace Davison, Cambridge, MA; (2) VLB Berlin, Berlin,<br />

Germany<br />

Recent studies have illustrated <strong>the</strong> use <strong>of</strong> electronic spin resonance<br />

(ESR) spectroscopy as an indicator <strong>of</strong> natural antioxidant<br />

concentration and flavor stability in beer. It is also possible to extend<br />

this technique to <strong>the</strong> evaluation <strong>of</strong> active packaging materials and<br />

<strong>the</strong> <strong>the</strong>ir impact on beer stability over <strong>the</strong> course <strong>of</strong> <strong>the</strong> shelf life. In<br />

this study, an evaluation <strong>of</strong> three different crown liner materials was<br />

conducted, correlating oxygen control with sensory analysis and<br />

ESR measurement <strong>of</strong> <strong>the</strong> beer’s endogenous antioxidant potential<br />

(EAP). As expected, beer packed under oxygen scavenging crown<br />

liners exhibited higher flavor stability through both measurement<br />

techniques, than that under non-scavenger controls. Fur<strong>the</strong>rmore,<br />

improvements to <strong>the</strong> oxygen reaction rates within <strong>the</strong> liners<br />

correlated with sensory and EAP improvements toward <strong>the</strong> latter<br />

half <strong>of</strong> <strong>the</strong> six-month shelf life. The oxidation <strong>of</strong> beer has been<br />

well attributed in <strong>the</strong> literature to <strong>the</strong> formation <strong>of</strong> unsaturated<br />

aldehydes, through several reaction mechanisms. Although <strong>the</strong><br />

mechanisms differ in <strong>the</strong>ir reactive components, <strong>the</strong>y all involve<br />

species formed from molecular oxygen, highlighting <strong>the</strong> importance<br />

<strong>of</strong> oxygen control both in <strong>the</strong> brewing process and <strong>the</strong> beer package.<br />

As <strong>the</strong> reaction rate <strong>of</strong> <strong>the</strong> oxygen scavenging crown liner is<br />

improved, it consumes oxygen at a rate that is more competitive with<br />

<strong>the</strong> natural uptake <strong>of</strong> oxygen in beer, and flavor stability over time is<br />

enhanced.<br />

Greg Pollock has been with W.R. Grace since July 2005, working in<br />

<strong>the</strong> Closure Sealants R&D group for Grace Davison Materials and<br />

Packaging Technologies (formerly Darex). During that time, he has<br />

supported <strong>the</strong> growing oxygen-scavenging technology business,<br />

by developing <strong>the</strong> new Celox faster oxygen-scavenging sealants,<br />

providing customer technical support on oxygen-scavenging<br />

technology and helping to identify and validate new opportunities<br />

for active packaging beyond sealants for beer bottles. Prior to<br />

joining Grace, Greg received a B.S. degree from <strong>the</strong> University <strong>of</strong><br />

Texas at Austin and a Ph.D. degree from <strong>the</strong> Massachusetts Institute<br />

<strong>of</strong> Technology, both in chemical engineering. While at MIT, Greg<br />

worked as a research assistant in <strong>the</strong> U.S. Army-funded Institute for<br />

Soldier Technologies, where he did his <strong>the</strong>sis work on <strong>the</strong> syn<strong>the</strong>sis<br />

and characterization <strong>of</strong> silk-inspired <strong>the</strong>rmoplastic polyurethane<br />

elastomers.<br />

P-178<br />

Development <strong>of</strong> a new sensor to control bottle conveyors<br />

ANDRE SORGATZ (1), Horst-Christian Langowski (1), Tobias Voigt<br />

(1), Axel Ka<strong>the</strong>r (1)<br />

(1) Technische Universität München, Freising, Germany<br />

In modern bottling plants a variety <strong>of</strong> machines are working<br />

toge<strong>the</strong>r. Each machine in <strong>the</strong> plant executes a specific function.<br />

To make <strong>the</strong> single machines work, bottles have to be transported<br />

from one machine to <strong>the</strong> next. For this conveyors are installed.<br />

The conveyors are commonly used as buffers as well. They have <strong>the</strong><br />

functionality to compensate for <strong>the</strong> downtime <strong>of</strong> a single machine.<br />

There are two types <strong>of</strong> buffers: <strong>the</strong> so called anti-starve buffer<br />

supplies bottles to <strong>the</strong> next machine while <strong>the</strong> machine before it<br />

has a breakdown. The anti-block buffer absorbs bottles during<br />

<strong>the</strong> breakdown <strong>of</strong> <strong>the</strong> following machine. Integrating <strong>the</strong>se buffer<br />

types in a bottling plant can reduce plant downtime caused by<br />

short downtimes <strong>of</strong> single machines. Following this strategy, it is<br />

important to control buffers correctly. Nowadays <strong>the</strong> filling level<br />

<strong>of</strong> buffers is detected by inductive or capacitive switches which are<br />

activated by <strong>the</strong> accumulating bottles. The disadvantage <strong>of</strong> this<br />

method is that <strong>the</strong> fill factor is determined only in steps. So <strong>the</strong><br />

speed <strong>of</strong> <strong>the</strong> conveyor can be changed only stepwise. Simulation<br />

studies at <strong>the</strong> Chair <strong>of</strong> Food Packing Technology showed that it<br />

would be better to change <strong>the</strong> speed continuously. Following this<br />

<strong>the</strong> efficiency <strong>of</strong> <strong>the</strong> plant could increase up to 5%. For this concept<br />

<strong>of</strong> a continuous control a new sensor is needed, which is able to<br />

count grouped bottles. Two kinds <strong>of</strong> sensors have been developed<br />

at <strong>the</strong> Chair <strong>of</strong> Food Packing Technology. One is a combination <strong>of</strong><br />

standard sensors with a PLC (programmable logic control), <strong>the</strong><br />

o<strong>the</strong>r is based on a CMOS-camera (complementary metal oxide<br />

semiconductor), which takes pictures <strong>of</strong> <strong>the</strong> passing bottles. The<br />

analysis <strong>of</strong> <strong>the</strong> pictures is performed by a special processor unit<br />

based on a FPGA (field programmable gate array). This intelligent<br />

camera transmits <strong>the</strong> number <strong>of</strong> counted bottles to <strong>the</strong> PLC, which<br />

calculates <strong>the</strong> correct speed <strong>of</strong> <strong>the</strong> conveyors. First experiments with<br />

different sensor systems also showed o<strong>the</strong>r advantages <strong>of</strong> this kind <strong>of</strong><br />

control: reduction <strong>of</strong> noise by <strong>the</strong> slower impact speed <strong>of</strong> <strong>the</strong> bottles;<br />

reduction <strong>of</strong> abrasion <strong>of</strong> <strong>the</strong> bottles (scuffing); higher utilization <strong>of</strong><br />

<strong>the</strong> buffer area.<br />

André Sorgatz (born 1980) trained as a brewer and maltster from<br />

September 2001 until June 2003 at <strong>the</strong> Paulaner brewery in Munich.<br />

In June 2003 he graduated and became a Munich <strong>Master</strong> <strong>of</strong> Young<br />

<strong>Brewers</strong> and <strong>Master</strong> <strong>of</strong> <strong>the</strong> South Bavarian <strong>Brewers</strong> Champion. After<br />

that he studied from 2003 until 2007 at <strong>the</strong> Technische Universität<br />

München/Weihenstephan. In November 2007 he graduated as an<br />

engineer with a Dipl.-Ing. degree in brewing science and beverage<br />

technology. In December 2007 he started working as doctoral<br />

candidate and research associate at <strong>the</strong> Chair <strong>of</strong> Food Packaging<br />

Technology, Technische Universität München. His fields <strong>of</strong> activity at<br />

<strong>the</strong> university include development <strong>of</strong> a new sensor to control bottle<br />

conveyors, control <strong>of</strong> conveyors at bottling plants, and reduction <strong>of</strong><br />

noise at bottling plants.<br />

153

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