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Program Book - Master Brewers Association of the Americas

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Technical Session VII: Cereals/Pseudocereals<br />

Moderator: Mary-Jane Maurice, ADM Malting LLC, Milwaukee, WI<br />

Mary-Jane Maurice is director <strong>of</strong> quality assurance for ADM Malting<br />

in Milwaukee, WI. Her responsibilities include management <strong>of</strong> all<br />

barley and malt analysis, performance <strong>of</strong> process audits, and data<br />

interpretation and problem solving for manufacturing. She received<br />

a B.S. degree in chemistry from Mount Mary College in 1990, and<br />

her entire career has been spent in <strong>the</strong> malting industry. In addition<br />

to ASBC and MBAA memberships, Mary-Jane also participates in<br />

<strong>the</strong> Quality Evaluation Sub-committee and Technical Committee at<br />

<strong>the</strong> American Malting Barley <strong>Association</strong>, Inc. and is a member <strong>of</strong><br />

<strong>the</strong> Board <strong>of</strong> Directors for <strong>the</strong> Brewing and Malting Barley Research<br />

Institute (Canada). Mary-Jane is also on <strong>the</strong> faculty <strong>of</strong> <strong>the</strong> World<br />

Brewing Academy (formerly Siebel Institute <strong>of</strong> Technology) in<br />

Chicago, IL. She received her malting diploma from The Maltsters’<br />

<strong>Association</strong> <strong>of</strong> Great Britain in 2004, a distinction held by only 80<br />

individuals in <strong>the</strong> world.<br />

O-24<br />

Application <strong>of</strong> alternate cereals and pseudocereals as a raw<br />

material with functionality for <strong>the</strong> brewing process and final<br />

beer<br />

MARTIN ZARNKOW (1), Cem Schwarz (1), Felix Burberg (1),<br />

Werner Back (1), Elke Arendt (2), Stefan Kreisz (3), Martina Gastl<br />

(1)<br />

(1) Lehrstuhl für Technologie der Brauerei I, Technische Universität<br />

München-Weihenstephan, Freising; (2) Department <strong>of</strong> Food and<br />

Nutritional Sciences, National University <strong>of</strong> Ireland, University<br />

College Cork, Cork, Ireland; (3) Novozymes AS, Bagsvaerd,<br />

Køpenhavn, Denmark<br />

In a worldwide view barley is <strong>the</strong> number one brewing cereal.<br />

Never<strong>the</strong>less <strong>the</strong>re is a wide range <strong>of</strong> common and less common<br />

cereals (corn, emmer, einkorn, durum wheat, millets, oat, rice, rye,<br />

sorghum, spelt, teff, triticale, tritordeum, wheat) and pseudocereals<br />

(amaranth, buckwheat, quinoa), which can be successfully<br />

substituted for barley or barley malt as brewing material. Some<br />

<strong>of</strong> <strong>the</strong>m, like rice, corn, millet and sorghum, are <strong>of</strong>ten used as<br />

brewing adjunct. Cereals like wheat, rye, oat, emmer, einkorn are<br />

sometimes used as adjunct or malt for special top fermented beers.<br />

All <strong>of</strong> <strong>the</strong>m have a wide range <strong>of</strong> functions, like enhancing foam<br />

stability, antioxidative potential, stability <strong>of</strong> turbidity, color impact,<br />

advancing lautering process, increasing zinc content, increasing<br />

secondary plant ingredients (e.g. rutin), development <strong>of</strong> special<br />

flavor and flavor stability, upgrading microbiology stability and<br />

development <strong>of</strong> gluten-free beverages. This work focuses on <strong>the</strong>se<br />

functions and shows <strong>the</strong> different functionalities <strong>of</strong> <strong>the</strong> different<br />

cereals and pseudocereals.<br />

Martin Zarnkow apprenticed as a brewer and maltster from 1989<br />

to 1991 at a small brewery in Frankonia. Zarnkow finished a Dipl.-<br />

Ing. (FH) degree with an option in brewing technology in 1996 at<br />

TU München Weihenstephan. Zarnkow worked as a brew master<br />

for one year in a medium-sized brewery in Germany. Since 1997,<br />

Martin has been a scientific assistant and head <strong>of</strong> <strong>the</strong> beer laboratory<br />

at <strong>the</strong> Lehrstuhl für Technologie der Brauerei I at <strong>the</strong> TU München<br />

Weihenstephan. Since September 2005 Martin has been working as<br />

a Ph.D. research fellow at <strong>the</strong> University College <strong>of</strong> Cork, Ireland on<br />

“Malting and Brewing with Non-traditional Cereals.”<br />

76<br />

O-25<br />

Malting and brewing with buckwheat—A gluten-free<br />

alternative<br />

ALEXANDER MAUCH (1), Blaise Nic Phiarais (1), Martin Zarnkow<br />

(2)<br />

(1) Department <strong>of</strong> Food and Nutritional Sciences, National<br />

University <strong>of</strong> Ireland, University College Cork, Ireland; (2)<br />

Lehrstuhl für Technologie der Brauerei I, Technische Universität<br />

München-Weihenstephan, Freising<br />

Celiac disease (CD) is an inflammatory disorder <strong>of</strong> <strong>the</strong> upper small<br />

intestine and is caused by <strong>the</strong> ingestion <strong>of</strong> specific cereal storage<br />

proteins in genetically susceptible individuals. Current studies<br />

show that approximately 0.9 to 1.2% <strong>of</strong> <strong>the</strong> Western population<br />

suffers from this affliction. For those who suffer from CD, <strong>the</strong> only<br />

safe alternative is to avoid <strong>the</strong> ingestion <strong>of</strong> gluten-containing or<br />

gluten-contaminated food and beverages, resulting in a need to<br />

develop alternatives, for example, to beer based on barley malt.<br />

This presentation gives an overview <strong>of</strong> a novel approach for <strong>the</strong><br />

development <strong>of</strong> gluten-free buckwheat malt and its subsequent use<br />

in <strong>the</strong> brewing process. Buckwheat (Fagopyrum esculentum) is a<br />

pseudocereal from <strong>the</strong> family Polygonaceae. It is a rich source <strong>of</strong><br />

starch and contains many valuable compounds, such as high quality<br />

protein and polyunsaturated fatty acids, antioxidant substances<br />

and dietary fiber and, <strong>the</strong>refore, is recommended as an ingredient<br />

for functional food products. Fur<strong>the</strong>rmore buckwheat is glutenfree<br />

and, <strong>the</strong>refore, acceptable for <strong>the</strong> diet <strong>of</strong> CD sufferers. This<br />

presentation comprises a detailed characterization <strong>of</strong> buckwheat<br />

and its assessment as a potential raw material for malting. For this,<br />

optimization <strong>of</strong> malting parameters in terms <strong>of</strong> improving typical<br />

malt-quality characteristics (e.g. fermentability, extract, free amino<br />

acids, viscosity, etc.) using ma<strong>the</strong>matical modeling is discussed in<br />

detail. Fur<strong>the</strong>rmore, variances <strong>of</strong> some functional constituents as<br />

well as <strong>the</strong> detection <strong>of</strong> ultra structural changes in <strong>the</strong> endosperm<br />

using advanced microscopy during malting are shown. Special<br />

emphasis is placed on <strong>the</strong> brewing process, which was performed<br />

on a 1000 L pilot scale plant with 100% buckwheat malt. A full<br />

flavor analysis combined with a sensory evaluation <strong>of</strong> <strong>the</strong> final beer<br />

was performed. Processing problems with saccharification, mash<br />

filtration and clarification during beer maturation, as well as beer<br />

filtration, due to <strong>the</strong> specific characteristics <strong>of</strong> buckwheat malt,<br />

like high gelatinization temperature, high viscosity, low enzymatic<br />

activity and flat husks, were expected. Results show that <strong>the</strong> low<br />

amylolytic potential <strong>of</strong> buckwheat malt could be overcome without<br />

problems by <strong>the</strong> use <strong>of</strong> industrial brewing enzymes. Fur<strong>the</strong>rmore,<br />

mash filtration and clarification during beer maturation could<br />

be enhanced by <strong>the</strong> addition <strong>of</strong> rice husks and viscosity lowering<br />

enzymes. However, it is necessary to recognize that fur<strong>the</strong>r<br />

optimization <strong>of</strong> buckwheat malting is required to achieve higher<br />

cytolyses. Notwithstanding <strong>the</strong>se issues, it is expected that once <strong>the</strong><br />

processing problems have been overcome, buckwheat beer will find<br />

acceptance with time, particularly among those who suffer from CD.<br />

Alexander Mauch completed an apprenticeship as a brewer and<br />

maltster in 2000 and worked in German and Swedish breweries<br />

until 2002. He <strong>the</strong>n studied at <strong>the</strong> Technische Universitaet Muenchen-<br />

Weihenstephan and received a M.S. degree in brewing and beverage<br />

technology in 2007. During his master <strong>the</strong>sis studies on “Proso Millet<br />

(Panicum miliaceum L.): A Review and Evaluation <strong>of</strong> <strong>the</strong> Ultrastructural<br />

Changes During Malting-Process by Using Scanning-<br />

Electron and Confocal Laser Microscopy,” he worked in <strong>the</strong> field<br />

<strong>of</strong> malting with minor cereals. In June 2007, Alexander began<br />

working on his Ph.D. <strong>the</strong>sis, which is investigating <strong>the</strong> impact <strong>of</strong><br />

different lactobacillus strains as starter cultures in malting in terms<br />

<strong>of</strong> inhibition <strong>of</strong> rootlet and mold growth. Fur<strong>the</strong>rmore, he is jointly

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