Letno poročilo 2005

vpliv interakcij med komplementarnimi
funkcionalnimi skupinami na heterogenost
segmentnega gibanja in na fazne prehode.
- Delo na ionsko prevodnih polimernih
membranah smo nadaljevali s pripravo sklopa
membrane in elektrod (angl. Membrane electrode
assembly, MEA), s katerim smo
preizkusili delovanje lastnih membran v testni
postaji in dolo~ili njihove elektrokemijske
lastnosti.
- Po poliolnem postopku smo sintetizirali
(nano)delce bakrovega (I) oksida, kovinskega
bakra in srebra, cinkovega oksida in nano`i~ke
Cu O v razli~nih diolih. Delci velikosti med 100
2
nm in 10 mm so bili ve~inoma aglomerirani,
na povr{ini pa je bilo adsorbirano topilo, ki
hkrati {~iti delce pred oksidacijo in omogo~a
bolj{o disperzibilnost delcev v organskih
medijih.
- Nanokompozite iz modificiranega montmorilonita
(MMT) in PMMA smo pripravili v
SLIKA 1:
Dvopol`ni ekstruder Teach-Line ZK 25T z vodno
kopeljo in granulatorjem, Dr. Collin.
Laboratorij za polimerno kemijo in tehnologijo
Laboratory for Polymer Chemistry and Technology
- The molecular dynamics of semi-interpenetrating
polymer networks and polymer mixtures
based on functionalised polyurethanes
and methacrylic copolymers was investigated
by electron spin resonance – spin label
method. The influence of polymer interactions
imposed by complementary functional
groups on motional heterogeneity and phase
transitions was confirmed.
- The research on ion-conducting polymer
membranes was focused on the preparation
of membrane-electrode assemblies (MEA)
which were used to test the electrochemical
characteristics of our own membranes in a
fuel cell test station.
- (Nano)particles of copper (I) oxide, metallic
copper, silver, zinc oxide and nanowires of
copper (I) oxide were synthesized by the
polyol procedure in different diols. Particles
with sizes between 100 nm and 10 mm were
mostly agglomerated. Solvent (diol) was
FIGURE 1:
Twin screw extruder Teach-Line ZK 25T with water
bath and strand pelletizer, Dr. Collin.
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