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Nanotechnology-Enabled Sensors

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3.5 Solid State Transducers 115<br />

and source and drain and source, respectively. Furthermore, the threshold<br />

voltage, Vt, is defined as: 25,26<br />

φ −φ<br />

Q + Q + Q<br />

= , (3.81)<br />

m s ox ss b<br />

Vt −<br />

+ 2φ<br />

f<br />

q Cox<br />

where φm and φs are the metal and semiconductor workfunctions respectively.<br />

Qox Qss and Qb are the accumulated charges in the oxide, oxide/<br />

semiconductor interface, and the depletion charge in the semiconductor,<br />

respectively. Finally, the last term, φf, depends on the doping level of the<br />

semiconducting material. As a consequence Vt being dependent on charge<br />

and capacitance, a FETs I-V characteristics are strongly affected by<br />

changes in humidity, ions, chemical species and the presence of dielectric<br />

materials in the environment.<br />

FETs may be implemented for applications in liquid media, as shown in<br />

Fig. 3.40, in which the metal gate is replaced with a reference electrode in<br />

a liquid touching the gate metal oxide layer. Insulating layers are added to<br />

isolate the connections to the drain and source from the liquid. A sensitive<br />

layer is deposited over the oxide layer, forming the gate, and as a result of<br />

chemical reactions occurring on this surface when free electrons or holes<br />

in the semiconductor become attracted or repelled to the gate surface.<br />

Fig. 3.40 A schematic representation of an ISFET.

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