Environmental Statement - Maersk Oil
Environmental Statement - Maersk Oil
Environmental Statement - Maersk Oil
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6.5. ENVIRONMENTAL RISKS ‐ FATE OF OIL IN THE MARINE ENVIRONMENT<br />
6 ‐ 24<br />
Balloch Field Development <strong>Environmental</strong> <strong>Statement</strong><br />
Section 6 Accidental Spills<br />
When crude oil is spilled on the surface of the sea it is subjected to a number of processes. These<br />
include spreading, evaporation, dissolution, emulsification, natural dispersion, photo‐oxidation,<br />
sedimentation and biodegradation. The fate and effect of crude oil is dependent on the chemical and<br />
physical properties of the oil. This is taken into account in the modelling scenarios.<br />
The physico‐chemical changes to which the oil is subjected vary depending on oil type, volume spilled<br />
and the prevailing weather and sea conditions. Some of these changes can lead to its disappearance<br />
from the sea surface while others, for example emulsification, may cause it to persist.<br />
Evaporation and dispersion are the two main mechanisms that act to remove oil from the sea surface.<br />
Evaporation is the main mechanism by which the mass of oil is reduced immediately after a spill. It<br />
also causes considerable changes in the density, viscosity and volume of the spill over time. The light<br />
fractions of the oil (aromatic compounds such as benzene and toluene) evaporate quickly.<br />
Substances like diesel (the most likely type of hydrocarbon to be spilled) have a greater percentage of<br />
light hydrocarbon fractions and will therefore evaporate relatively quickly in comparison with heavier<br />
oils. A large proportion of even a very large spill of diesel will evaporate within the first 24 hours of<br />
release. Evaporation is enhanced by warm air temperatures and moderate winds. The oil remaining<br />
in the slick will have a higher viscosity and specific gravity. The processes of dissolution, dispersion<br />
and photo‐oxidation will also act to break down the oil. The aromatic compounds of diesel can be<br />
toxic to planktonic organisms in the vicinity of the spill.<br />
Figure 6‐14 Fate and behaviour of spilled oil at sea (adapted from Koops, 1985).<br />
After the light fractions have evaporated from the slick, the process slows down and natural<br />
dispersion becomes the dominant mechanism in reducing the slick volume. This process is dependent<br />
upon sea surface turbulence, which in turn is affected by wind speed. Water‐soluble components of<br />
the oil mass will dissolve in the seawater and the immiscible components will either emulsify and