APPENDIX F Threats to <strong>Groundwater</strong> Quality <strong>in</strong> <strong>the</strong> <strong>Great</strong> <strong>Lakes</strong> Bas<strong>in</strong> — Hazardous Waste Sites CONTENTS INTRODUCTION 84 GROUNDWATER CONTAMINATION 84 HUMAN HEALTH EFFECTS 85 SITE ASSESSMENT 85 THE NIAGARA RIVER AREA OF CONCERN 86 LEGISLATION 88 HAZARDOUS WASTE INJECTION WELLS 90 BASINWIDE REMEDIATION AND PREVENTION 90 REFERENCES AND BIBLIOGRAPHY 91 GLOSSARY 93 83
INTRODUCTION 84 Hazardous wastes are generally def<strong>in</strong>ed as materials, <strong>in</strong>clud<strong>in</strong>g liquids, solids and gases, that are dangerous or potentially dangerous to environmental or human health. Hazardous wastes are identified as hav<strong>in</strong>g one or more of <strong>the</strong> follow<strong>in</strong>g properties: ignitability, corrosivity, reactivity or toxicity (U.S. EPA, 2006a). The U.S. Environmental Protection Agency (EPA) has compiled a list conta<strong>in</strong><strong>in</strong>g more than 500 hazardous wastes (U.S. EPA, 2006c). Accord<strong>in</strong>g to <strong>the</strong> U.S. EPA (2006c) more than 40 million tons of hazardous wastes are produced <strong>in</strong> <strong>the</strong> U.S. every year. However, o<strong>the</strong>r sources <strong>in</strong>dicate that this figure might be as high as six billion tons (Natural Resource Council on Environmental Epidemiology, 1991). Canada produces more than six million tons of hazardous waste per year (Environment Canada, 2003). Hazardous waste sites are deemed potentially dangerous if not properly ma<strong>in</strong>ta<strong>in</strong>ed because <strong>the</strong>y hold <strong>the</strong> potential to release irritant gases, metals, solvents, pesticides and many o<strong>the</strong>r harmful substances. These substances can easily migrate away from <strong>the</strong> site contam<strong>in</strong>at<strong>in</strong>g <strong>the</strong> surround<strong>in</strong>g air, soil and water (both above and below ground). Many examples of groundwater contam<strong>in</strong>ation result<strong>in</strong>g from hazardous waste dumps can be found <strong>in</strong> <strong>the</strong> literature, <strong>in</strong>clud<strong>in</strong>g many <strong>in</strong> <strong>the</strong> <strong>Great</strong> <strong>Lakes</strong> region, especially <strong>in</strong> <strong>the</strong> Niagara Falls area (Love Canal, Hyde Park, etc.) (Fletcher, 2002). Hazardous waste production began to <strong>in</strong>crease <strong>in</strong> <strong>the</strong> 1940s along with <strong>in</strong>dustrial expansion and <strong>the</strong> chemical revolution (Government of Canada, 2002). Dur<strong>in</strong>g <strong>the</strong> 1940s and 1950s land disposal of hazardous waste <strong>in</strong> Figure 1. unl<strong>in</strong>ed landfills and lagoons was common <strong>in</strong>dustrial practice. In many cases, <strong>the</strong>se practices cont<strong>in</strong>ued <strong>in</strong>to <strong>the</strong> 1980s. As a result <strong>the</strong>re are currently more than 4,500 known hazardous waste sites <strong>in</strong> <strong>the</strong> <strong>Great</strong> <strong>Lakes</strong> Bas<strong>in</strong>. Of <strong>the</strong> known sites, 98% are <strong>in</strong> <strong>the</strong> United States and 2% <strong>in</strong> Canada (Fletcher, 2003). Of <strong>the</strong> previously estimated total, only 6% are still open and accept<strong>in</strong>g waste (Fletcher, 2003). Currently <strong>the</strong>re is only one operat<strong>in</strong>g commercial hazardous waste landfill <strong>in</strong> Ontario, located near Sarnia (Fletcher, 2003). GROUNDWATER CONTAMINATION The density distribution of hazardous waste sites varies considerably across <strong>the</strong> bas<strong>in</strong> (Figure 1). Some of <strong>the</strong> highest densities are located <strong>in</strong> <strong>the</strong> Detroit, Michigan, and Niagara Falls, New York, areas where <strong>the</strong>re is more than 1 site per 13 square kilometers (Fletcher, 2003). In contrast, <strong>in</strong> <strong>the</strong> adjo<strong>in</strong><strong>in</strong>g Canadian areas, <strong>the</strong> densities are much lower with less than 1 site per 52 square kilometers <strong>in</strong> Lambton County, Ontario, and less than 1 site per 259 square kilometers <strong>in</strong> Niagara Falls, Ontario (Fletcher, 2003). Hazardous waste sites are a significant concern to water quality of <strong>the</strong> <strong>Great</strong> <strong>Lakes</strong>. Precipitation that has come <strong>in</strong> contact with hazardous waste percolates down through <strong>the</strong> earth, contam<strong>in</strong>at<strong>in</strong>g groundwater supplies that serve to recharge <strong>the</strong> lakes. Significant groundwater contam<strong>in</strong>ation has occurred at <strong>the</strong> FMC Density distribution of waste sites <strong>in</strong> <strong>the</strong> <strong>Great</strong> <strong>Lakes</strong> Bas<strong>in</strong> Sources: IJC, 1993; U.S. EPA CERCLA Data, 1990; U.S. EPA RCRA Data, 1992; MOE Inventory Data, 1990 Corporation Dubl<strong>in</strong> Road Site, an <strong>in</strong>active waste site located <strong>in</strong> Orleans County of northwestern New York. From 1933 to 1968, debris, <strong>in</strong>clud<strong>in</strong>g laboratory wastes, pesticides and chemical residues, was disposed lead<strong>in</strong>g to water and soil contam<strong>in</strong>ation. Lead, mercury, arsenic and pesticides have been identified result<strong>in</strong>g <strong>in</strong> <strong>the</strong> construction of a groundwater extraction treatment system and an on-site water treatment facility. Over <strong>the</strong> next 20 to 30 years approximately 126 million gallons of groundwater will need to be treated (U.S. EPA, 2006d).
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AReportoftheGreatLakesScienceAdviso
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Citation: Great Lakes Science Advis
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Commissioners’ Preface The Great
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8 Transmittal Letter Groundwater/An
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APPENDICES Appendices A through L p
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INTRODUCTION Groundwater, a major n
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24 PATHOGENS Bacteria, viruses and
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Viruses Viral pathogens continue to
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SPECIFIC EPISODES Walkerton In 2000
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30 season. The sampling sites inclu
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134 Levy, S. (2004, November 16). T
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INTRODUCTION 142 Groundwater law ac
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150 Chapter 1501:15 Soil and Water
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APPENDIX M List of Acronyms ADHD -