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RESEARCH· ·1970·

RESEARCH· ·1970·

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B208. GROUND-WATER CONTAMINATION<br />

facilitated by study of water levels, a largely neglected<br />

technique in southeastern Connecticut.<br />

The sequence in which the wells produced waterborne<br />

styrene indicates how water moves through the bedrock.<br />

Six wells are reported to have produced water<br />

with recognizable styrene odor, in the following order:<br />

Ly 291, Ly 219, Ly 217, Ly 218, Ly 220, and Ly 221.<br />

The early arrival of waterborne styrene in the .fh·st two<br />

wells, Ly 291 and Ly 219, is attributed to their closeness<br />

to the eastern burial site, where bedrock was reportedly<br />

struck at a depth of 6 to 8 feet below the road<br />

surface, and where styrene-contaminated soil and fill<br />

were found to extend down to bedrock. ~1ovement of<br />

waterborne styrene is believed to have been largely<br />

north-northeastward, downdip along north-dipping foliation<br />

joints. Movement dominantly along cross joints<br />

is considered unlikely because they are vertical or near<br />

vertical, and the log for Ly 291 indicates that it penetrated<br />

four water-bearing fractures in an apparent<br />

thickness of only 88 feet of bedrock. Within the foliation<br />

joints, however, movement was undoubtedly more<br />

rapid at their intersections with cross joints; these<br />

larger openings, by their geometry, formed northeastplunging<br />

pipes. Even in the unlikely possibility that<br />

the contaminating slug was confined to these pipes and<br />

did not spread out as it moved downdip about 75 feet<br />

(about 50 feet horizontally), it would have been very<br />

close to the two wells-about 15 feet from Ly 291 and<br />

about 20 feet from Ly 219. Ly 219 responded much<br />

more strongly to local recharge (rainfall) than did<br />

Ly 291, as shown in figure 2. Its greater sensitivity is<br />

presumably due to its larger cone of depression; its<br />

yield is only about a quarter that of Ly 291, and both<br />

supplied about the same amount of water for domestic<br />

needs. ·<br />

The third well, Ly 217, is about halfway between the<br />

two sources of contamination and updip from both, if<br />

movement is thought to have taken place solely along<br />

foliation joints. As ground water presumably moved<br />

westward along foliation joints in the schist toward<br />

the Thames estuary, pumping from Ly 217 would expand<br />

its cone of depression northward along northtrending<br />

cross joints, thereby intercepting the westmoving<br />

slug of contaminated water. It is possible, however,<br />

that another small source of styrene was buried<br />

in the area. Also, it is known that some subsurface<br />

water circulates above the bedrock surface. Omission<br />

of this aspect of the study, owing to incomplete data,<br />

is not believed to affect the validity of the conclusions<br />

developed here.<br />

Well Ly 305 is closer to the eastern source of contamination<br />

than Ly 217 but is farther south. Well Ly<br />

305 never produced waterborne styrene, either because<br />

of its location or because of a difference in the bedrock<br />

joint pattern; it is the only well in the immediate area<br />

known to tap quartzite. That the joints it penetrates<br />

are few and tight is · indicated by its yield of 2112<br />

gallons per minute, the lowest recorded in the area.<br />

Ly 218, the fourth well, is very close to the western<br />

burial site and may have been the only one contarninated<br />

by it. Its delayed response is due in part to the<br />

smaller size of the western contamination source and<br />

to delayed pumping-its users were the last of the six<br />

affected homeowners to take up residence. A puzzling<br />

feature of the western burial site is that contaminated<br />

soil extended to a depth of only 6 feet when it was<br />

excavated in November 1961, although digging continued<br />

to a depth of 10 feet.<br />

The fifth well to be affected, Ly 220, is situated at a<br />

greater distance from the eastern burial site than any<br />

of the previously affected wells. The overall flow -line<br />

distance to this well may be estimated by the algebraic<br />

addition of its three component movements : westward<br />

along foliation joints for a distance of about 110 feet,<br />

northward along vertical joints for about 60 feet, and<br />

diagonally downward for a~out 180 feet. The estimated<br />

total of about 350 feet is only an approximation; it is<br />

greater if flow lines followed a more circuitous route,<br />

and smaller if movement was largely along northplunging<br />

pipes formed by joint intersections, as previously<br />

indicated. Sheeting joints may have shortened<br />

the overall distance to this well, which taps granite<br />

gneiss. Ly 221 was the sixth and last well affected. It<br />

reportedly produced waterborne styrene only twice, in<br />

May 1962. Ly 307 was unused until March 1962 and,<br />

with the exception of Ly 305, was the only well in the<br />

immediate area unaffected by waterborne styrene.<br />

The sequence of decontamination in the wells corroborates<br />

some conclusions based on their contamination.<br />

As previously indicated, the western burial site<br />

was excavated in eady November 1961, and measurable<br />

styrene in water from Ly 218 disappeared after<br />

autumn 1962. The eastern burial site was excavated in<br />

October 1962, and no styrene was detected in water<br />

from Ly 291 after l\1arch 1963 nor from Ly 219 after<br />

September 1963. Ly 217, situated farther down the<br />

hydraulic gradient from the eastern site, yielded water<br />

samples with measurable styrene until autumn 1964.<br />

CONCLUSI·ONS<br />

( 1) Till and bedrock in southeastern Connecticut are<br />

vulnerable to contamination by hydrocarbons. Stratified<br />

drift-the principal aquifer-is believed to be<br />

more vulnerable because it is far more permeable than<br />

till or bedrock, and water is pumped from it at much<br />

higher rates.<br />

(2) Within the bedrock aquifer, waterborne hydrocarbons,<br />

as exemplified by styrene in this investigation,

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