RESEARCH· ·1970·
RESEARCH· ·1970·
RESEARCH· ·1970·
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B208. GROUND-WATER CONTAMINATION<br />
facilitated by study of water levels, a largely neglected<br />
technique in southeastern Connecticut.<br />
The sequence in which the wells produced waterborne<br />
styrene indicates how water moves through the bedrock.<br />
Six wells are reported to have produced water<br />
with recognizable styrene odor, in the following order:<br />
Ly 291, Ly 219, Ly 217, Ly 218, Ly 220, and Ly 221.<br />
The early arrival of waterborne styrene in the .fh·st two<br />
wells, Ly 291 and Ly 219, is attributed to their closeness<br />
to the eastern burial site, where bedrock was reportedly<br />
struck at a depth of 6 to 8 feet below the road<br />
surface, and where styrene-contaminated soil and fill<br />
were found to extend down to bedrock. ~1ovement of<br />
waterborne styrene is believed to have been largely<br />
north-northeastward, downdip along north-dipping foliation<br />
joints. Movement dominantly along cross joints<br />
is considered unlikely because they are vertical or near<br />
vertical, and the log for Ly 291 indicates that it penetrated<br />
four water-bearing fractures in an apparent<br />
thickness of only 88 feet of bedrock. Within the foliation<br />
joints, however, movement was undoubtedly more<br />
rapid at their intersections with cross joints; these<br />
larger openings, by their geometry, formed northeastplunging<br />
pipes. Even in the unlikely possibility that<br />
the contaminating slug was confined to these pipes and<br />
did not spread out as it moved downdip about 75 feet<br />
(about 50 feet horizontally), it would have been very<br />
close to the two wells-about 15 feet from Ly 291 and<br />
about 20 feet from Ly 219. Ly 219 responded much<br />
more strongly to local recharge (rainfall) than did<br />
Ly 291, as shown in figure 2. Its greater sensitivity is<br />
presumably due to its larger cone of depression; its<br />
yield is only about a quarter that of Ly 291, and both<br />
supplied about the same amount of water for domestic<br />
needs. ·<br />
The third well, Ly 217, is about halfway between the<br />
two sources of contamination and updip from both, if<br />
movement is thought to have taken place solely along<br />
foliation joints. As ground water presumably moved<br />
westward along foliation joints in the schist toward<br />
the Thames estuary, pumping from Ly 217 would expand<br />
its cone of depression northward along northtrending<br />
cross joints, thereby intercepting the westmoving<br />
slug of contaminated water. It is possible, however,<br />
that another small source of styrene was buried<br />
in the area. Also, it is known that some subsurface<br />
water circulates above the bedrock surface. Omission<br />
of this aspect of the study, owing to incomplete data,<br />
is not believed to affect the validity of the conclusions<br />
developed here.<br />
Well Ly 305 is closer to the eastern source of contamination<br />
than Ly 217 but is farther south. Well Ly<br />
305 never produced waterborne styrene, either because<br />
of its location or because of a difference in the bedrock<br />
joint pattern; it is the only well in the immediate area<br />
known to tap quartzite. That the joints it penetrates<br />
are few and tight is · indicated by its yield of 2112<br />
gallons per minute, the lowest recorded in the area.<br />
Ly 218, the fourth well, is very close to the western<br />
burial site and may have been the only one contarninated<br />
by it. Its delayed response is due in part to the<br />
smaller size of the western contamination source and<br />
to delayed pumping-its users were the last of the six<br />
affected homeowners to take up residence. A puzzling<br />
feature of the western burial site is that contaminated<br />
soil extended to a depth of only 6 feet when it was<br />
excavated in November 1961, although digging continued<br />
to a depth of 10 feet.<br />
The fifth well to be affected, Ly 220, is situated at a<br />
greater distance from the eastern burial site than any<br />
of the previously affected wells. The overall flow -line<br />
distance to this well may be estimated by the algebraic<br />
addition of its three component movements : westward<br />
along foliation joints for a distance of about 110 feet,<br />
northward along vertical joints for about 60 feet, and<br />
diagonally downward for a~out 180 feet. The estimated<br />
total of about 350 feet is only an approximation; it is<br />
greater if flow lines followed a more circuitous route,<br />
and smaller if movement was largely along northplunging<br />
pipes formed by joint intersections, as previously<br />
indicated. Sheeting joints may have shortened<br />
the overall distance to this well, which taps granite<br />
gneiss. Ly 221 was the sixth and last well affected. It<br />
reportedly produced waterborne styrene only twice, in<br />
May 1962. Ly 307 was unused until March 1962 and,<br />
with the exception of Ly 305, was the only well in the<br />
immediate area unaffected by waterborne styrene.<br />
The sequence of decontamination in the wells corroborates<br />
some conclusions based on their contamination.<br />
As previously indicated, the western burial site<br />
was excavated in eady November 1961, and measurable<br />
styrene in water from Ly 218 disappeared after<br />
autumn 1962. The eastern burial site was excavated in<br />
October 1962, and no styrene was detected in water<br />
from Ly 291 after l\1arch 1963 nor from Ly 219 after<br />
September 1963. Ly 217, situated farther down the<br />
hydraulic gradient from the eastern site, yielded water<br />
samples with measurable styrene until autumn 1964.<br />
CONCLUSI·ONS<br />
( 1) Till and bedrock in southeastern Connecticut are<br />
vulnerable to contamination by hydrocarbons. Stratified<br />
drift-the principal aquifer-is believed to be<br />
more vulnerable because it is far more permeable than<br />
till or bedrock, and water is pumped from it at much<br />
higher rates.<br />
(2) Within the bedrock aquifer, waterborne hydrocarbons,<br />
as exemplified by styrene in this investigation,