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Chapter 5 Published Results Table 5.1. Crystal Data <strong>and</strong> Structure Refinement for (Na-26) <strong>and</strong> (Na-27). Code Na-26 Na-27 Empirical formula H 130 Na 22 O 144 Te 4 W 20 H 52 Na 14 O 80 Te W 15 MW 7172.18 4539.42 Crystal system Triclinic Orthorhombic Space group (no.) P1̅ (2) Pccn aÅ 12.741(2) 11.8841(5) bÅ 16.842(3) 20.8934(11) cÅ 17.197(4) 31.801(2) ° 93.961(10) 90 ° 107.466(8) 90 ° 108.548(8) 90 V/Å 3 3281.5(11) 7896.3(7) Z 1 4 T/ ºC -100(2) -100(2) λÅ 0.71073 0.71073 D/ Mg m -3 3.629 3.753 μ/ mm -1 18.53 22.29 R[I >2sigma(I)] a 0.037 0.074 R w (all data) b 0.100 0.225 ______________________________________________ a R = ∑|F o | – |F c | |∑| |F o |. b R w = {∑[w(F 2 o – F 2 c ) 2 ] / ∑[w(F 2 o ) 2 ]} 1/2 . 169
Chapter 5 Published Results Table 5.2. Te–O(W) Bond Lengths (Å) for Na-26. Te1 Å Te2 Å Te – O5TE 1.853(6) Te – O10E 1.853(6) Te – O12T 1.884(6) Te – O6TE 1.859(6) Te – O24T 1.986(6) Te – O789 2.061(6) Te – O6T 2.332(6) Te – O5A 2.199(6) Table 5.3. Selected Bond Angles (/°) for Na-26. Te1 /° Te2 /° O5TE– Te1– O12T 97.8(3) O10E–Te2–O6TE 99.6(3) O5TE– Te1–O24T 94.9(3) O10E–Te2–O789 92.2(3) O12T–Te1–O24T 90.6(3) O6TE–Te2–O789 88.1(3) O5TE–Te1– O6T 82.1(2) O10E–Te2–O5A 83.7(3) O12T–Te1–O6T 81.2(2) O6TE–Te2–O5A 83.8(3) O24T–Te1–O6T 170.8(2) O789–Te2–O5A 170.1(2) Table 5.4. Selected W–O Bond Lenghths (Å) for Na-26. W–O Å W–O Å W1–O1T W1– O14 W1– O110 W1– O123 W1– O12 W1– O12T 1.716(7) 1.787(6) 1.867(7) 1.974(6) 2.111(6) 2.382(6) W7–O7T W7–O710 W7–O67 W7–O79 W7–O78 W7–O789 1.743(6) 1.822(6) 1.882(6) 1.890(6) 2.098(6) 2.338(6) W2–O2T W2–O2A W2–O12 W2–O23 W2–O123 W2–O12T 1.738(7) 1.780(7) 1.883(6) 1.952(6) 2.092(6) 2.385(6) W8–O8T W8–O8A W8–O68 W8–O89 W8–O78 W8–O789 1.752(7) 1.759(7) 1.895(6) 1.967(6) 2.215(6) 2.217(6) 170
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