Synthesis and Structural Characterization of ... - Jacobs University

More documents

Recommendations

Info

Chapter 5 Published Results Figure 5.3. Polyhedral representation of the [HTe 2 W 10 O 40 ] 11− half-unit of 26. The color code is as follows: WO 6 octahedra (green, light blue, pink, red); Te (blue); O (red). The WO 6 octahedra were colored differently for clarity. See also text and Figure 5.4. The eight Te– O(W) bond distances range from 1.853(6) to 2.332(6) Å. The decatungstate {W 10 } unit can be considered as an assembly of four types of ‘building blocks’ (see Figure 5.4): - One tritungstate {W 3 } fragment (green in Figure 5.4) made of three edge-shared [WO 6 ] octahedra connected via a μ 3 -oxo bridge. This fragment can be viewed as a single ‘triad’ of the well-known Keggin and Wells-Dawson structures. 1a - One ditungstate {W 2 } subunit (light blue in Figure 5.4) made of two face-shared [WO 6 ] octahedra connected via three μ 2 -oxo bridges. This feature is very rare in POM chemistry. 1a Face-shared W VI O 6 octahedra result in large coulombic repulsion between the highly positively charged metal centers. In 26, the separation between the faceshared tungsten atoms (W1···W2) is 3.060(7) Å, shorter than the separations in corner-shared or edge-shared octahedra (approximately 3.7 and 3.4 Å, respectively). In 1968 Dexter and Silverton presented the first example of a polyanion containing 173
Chapter 5 Published Results face-shared octahedra, [CeMo 12 O 42 ] 8– . 14 This species consists of six pairs of faceshared octahedra (Mo 2 O 9 unit) {W 10 } half-unit of 26 OH {W 3 } subunit {W 1 } subunit {W 4 } subunit Figure 5.4. Polyhedral representation of the building blocks forming the decatungstate {W 10 } unit. The color code is as follow: W 3 (green), W 2 ; face-shared octahedra (light blue), W 2 ; edge-shared octahedra (pink), W 1 (red), oxygen (red), mono-protonated μ 2 -oxygen (rose). The four subunits were colored differently for clarification. 174
Page 1 and 2:
Synthesis and Structural Characteri
Page 3 and 4:
Amal H. Ismail Ph.D. Thesis Acknowl
Page 5 and 6:
Amal H. Ismail Ph.D. Thesis Abstrac
Page 7 and 8:
Amal H. Ismail Ph.D. Thesis 1.6.1 P
Page 9 and 10:
Amal H. Ismail Ph.D. Thesis 3.B.1.2
Page 11 and 12:
Amal H. Ismail Ph.D. Thesis 5.B.2.
Page 13 and 14:
Amal H. Ismail Ph.D. Thesis Figure
Page 15 and 16:
Amal H. Ismail Ph.D. Thesis (pink);
Page 17 and 18:
Page 19 and 20:
Page 21 and 22:
Amal H. Ismail Ph.D. Thesis List of
Page 23 and 24:
Amal H. Ismail Ph.D. Thesis K 8 Cs
Page 25 and 26:
Chapter 1 Introduction proposed a s
Page 27 and 28:
Chapter 1 Introduction A or B. At s
Page 29 and 30:
Chapter 1 Introduction c) [(H 2 )W
Page 31 and 32:
Chapter 1 Introduction by protonati
Page 33 and 34:
Chapter 1 Introduction structures;
Page 35 and 36:
Chapter 1 Introduction mono-, di-,
Page 37 and 38:
Chapter 1 Introduction Removal of t
Page 39 and 40:
Chapter 1 Introduction α-[P 2 W 18
Page 41 and 42:
Chapter 1 Introduction Figure 1.10
Page 43 and 44:
Chapter 1 Introduction In general,
Page 45 and 46:
Chapter 1 Introduction 1.6.1 Photoc
Page 47 and 48:
Chapter 1 Introduction dioxygen is
Page 49 and 50:
Chapter 1 Introduction 1.7 Lanthani
Page 51 and 52:
Chapter 1 Introduction ligand for o
Page 53 and 54:
Chapter 1 Introduction [Gd 8 As 12
Page 55 and 56:
Chapter 1 Introduction Recently, we
Page 57 and 58:
Chapter 1 Introduction P 2 W 16 O 5
Page 59 and 60:
Chapter 1 Introduction [7] L. C. Pa
Page 61 and 62:
Chapter 1 Introduction Malacria, C.
Page 63 and 64:
Chapter 1 Introduction [55] B. Nohr
Page 65 and 66:
Chapter 2 Experimental 2.2 Instrume
Page 67 and 68:
Chapter 2 Experimental 2.3.2 Synthe
Page 69 and 70:
Chapter 2 Experimental 2.3.8 Synthe
Page 71 and 72:
Chapter 2 Experimental 2.4 Referenc
Page 73 and 74:
Chapter 3 Published Results general
Page 75 and 76:
Chapter 3 Published Results 2.5 mL
Page 77 and 78:
Chapter 3 Published Results Na 8 [T
Page 79 and 80:
Chapter 3 Published Results matrix
Page 81 and 82:
Chapter 3 Published Results 3.A.1.4
Page 83 and 84:
Chapter 3 Published Results [H 2 W
Page 85 and 86:
Chapter 3 Published Results and one
Page 87 and 88:
Chapter 3 Published Results {W 4 }
Page 89 and 90:
Chapter 3 Published Results We also
Page 91 and 92:
Chapter 3 Published Results Figure
Page 93 and 94:
Chapter 3 Published Results We trie
Page 95 and 96:
Chapter 3 Published Results M. T. P
Page 97 and 98:
Chapter 3 Published Results 72.936(
Page 99 and 100:
Chapter 3 Published Results La, Ce,
Page 101 and 102:
Chapter 3 Published Results Na 8 Eu
Page 103 and 104:
Chapter 3 Published Results Table 3
Page 105 and 106:
Page 107 and 108:
Chapter 3 Published Results Polyani
Page 109 and 110:
Chapter 3 Published Results [LnW 10
Page 111 and 112:
Chapter 3 Published Results analogu
Page 113 and 114:
Chapter 3 Published Results We also
Page 115 and 116:
Chapter 3 Published Results example
Page 117 and 118:
Chapter 3 Published Results 1737; q
Page 119 and 120:
Chapter 3 Published Results 3.B. La
Page 121 and 122:
Chapter 3 Published Results expecte
Page 123 and 124:
Chapter 3 Published Results 3.B.1.3
Page 125 and 126:
Page 127 and 128:
Chapter 3 Published Results differe
Page 129 and 130:
Page 131 and 132:
Page 133 and 134:
Chapter 3 Published Results Acta 20
Page 135 and 136:
Chapter 3 Published Results Chem.,
Page 137 and 138:
Chapter 3 Unpublished Results bond
Page 139 and 140:
Chapter 3 Unpublished Results lanth
Page 141 and 142:
Chapter 3 Unpublished Results Na 10
Page 143 and 144:
Chapter 3 Unpublished Results Figur
Page 145 and 146: Chapter 3 Unpublished Results 3.B.2
Page 147 and 148: Chapter 3 Unpublished Results In po
Page 149 and 150: Chapter 3 Unpublished Results Figur
Page 153 and 154: Chapter 3 Unpublished Results (a) (
Page 155 and 156: Chapter 3 Unpublished Results param
Page 157 and 158: Chapter 3 Unpublished Results G.-F.
Page 159 and 160: Chapter 3 Unpublished Results Here
Page 163 and 164: Chapter 3 Unpublished Results This
Page 165 and 166: Chapter 3 Unpublished Results techn
Page 169 and 170: Chapter 4 Unpublished Results Chapt
Page 171 and 172: Chapter 4 Unpublished Results The c
Page 173 and 174: Chapter 4 Unpublished Results iron(
Page 175 and 176: Chapter 4 Unpublished Results 4.4.
Page 181 and 182: Chapter 4 Unpublished Results Therm
Page 183 and 184: Chapter 4 Unpublished Results This
Page 185 and 186: Chapter 4 Unpublished Results 4.6.
Page 187 and 188: Chapter 4 Unpublished Results S. Ba
Page 189 and 190: Chapter 5 Published Results Also te
Page 191 and 192: Chapter 5 Published Results 5.A.1.3
Page 193 and 194: Chapter 5 Published Results Table 5
Page 195: Chapter 5 Published Results [HTe 2
Page 199 and 200: Chapter 5 Published Results polymol
Page 201 and 202: Chapter 5 Published Results Each of
Page 203 and 204: Chapter 5 Published Results Althoug
Page 205 and 206: Chapter 5 Published Results Polyako
Page 207 and 208: Chapter 5 Unpublished Results 5.A.2
Page 209 and 210: Chapter 5 Unpublished Results 610(m
Page 211 and 212: Chapter 5 Unpublished Results 5.A.2
Page 215 and 216: Chapter 5 Unpublished Results {Mo 6
Page 217 and 218: Chapter 5 Unpublished Results compo
Page 219 and 220: Chapter 5 Unpublished Results [3] a
Page 221 and 222: Chapter 5 Published Results 5.B. Tr
Page 223 and 224: Chapter 5 Published Results H 2 O)
Page 225 and 226: Chapter 5 Published Results 5.B.3.
Page 227 and 228: Chapter 5 Published Results Each Ke
Page 229 and 230: Chapter 5 Published Results GeW 9 O
Page 231 and 232: Chapter 5 Published Results the axi
Page 233 and 234: Chapter 5 Published Results The man
Page 235 and 236: Chapter 5 Published Results 5.B.6.
Page 237 and 238: Chapter 5 Published Results [19] L.
Page 239: Amal H. Ismail Ph.D. Thesis Appendi
show all

Synthesis and Structural Characterization of ... - Jacobs University

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?