Synthesis and Structural Characterization of ... - Jacobs University

More documents

Recommendations

Info

Amal H. Ismail Ph.D. Thesis 2.3.10 Synthesis of K 6 [α-P 2 W 18 O 62 ] ·20H 2 O ....................................................................... 46 2.3.11 Synthesis of K 12 [H 2 P 2 W 12 O 48 ]·24H 2 O ...................................................................... 47 2.3.12 Synthesis of K 28 Li 5 [H 7 P 8 W 48 O 184 ]·92H 2 O ................................................................ 47 2.4 References .......................................................................................................................... 48 Chapter III Lanthanide-Containing POMs .............................................................................................. 49 3.A. Lanthanide-Containing Isopolytungstates: .................................................................. 49 3.A.1. The 22-Isopolytungstate Fragment [H 2 W 22 O 74 ] 14− Coordinated to Lanthanide Ions ....................................................................................................................................... 49 3.A.1.1. Introduction ........................................................................................................ 49 3.A.1.2. Synthesis ............................................................................................................. 51 3.A.1.3. X-ray Crystallography ........................................................................................ 55 3.A.1.4. Results and Discussion ....................................................................................... 58 3.A.1.5. Conclusions ........................................................................................................ 70 3.A.1.6. References .......................................................................................................... 71 3.A.2. The 28-Isopolytungstate Fragment [H 2 W 28 O 95 ] 20− Stabilized by two External Lanthanide Ions .................................................................................................................. 75 3.A.2.1. Introduction ........................................................................................................ 75 3.A.2.2. Synthesis ............................................................................................................. 77 3.A.2.3. X-ray Crystallography ........................................................................................ 79 3.A.2.4. Results and Discussion ....................................................................................... 81 3.A.2.5. Conclusions ........................................................................................................ 91 3.A.2.6. References .......................................................................................................... 92 3.B. Lanthanide-Containing Heteropolytungstates: ........................................................... 96 3.B.1. Mono- and Di-Lanthanide Derivatives of Tungstoarsenates(III) ....................... 96 3.B.1.1. Introduction ........................................................................................................ 96 vi
Amal H. Ismail Ph.D. Thesis 3.B.1.2. Synthesis ............................................................................................................. 99 3.B.1.3. X-ray Crystallography ...................................................................................... 100 3.B.1.4. Results and Discussion ..................................................................................... 102 3.B.1.5. Conclusions ...................................................................................................... 108 3.B.1.6. References ........................................................................................................ 109 3.B.2. Mono- and Di-Lanthanide Derivatives of Tungstoantimonate(III) .................. 113 3.B.2.1. Introduction ...................................................................................................... 113 3.B.2.2. Synthesis ........................................................................................................... 116 3.B.2.3. X-ray Crystallography ...................................................................................... 120 3.B.2.4. Results and Discussion ..................................................................................... 122 3.B.2.5. Conclusions ...................................................................................................... 131 3.B.2.6. References ........................................................................................................ 132 3.B.3. Lanthanide Substituted Polyoxoanions Containing Bridging Acetate Ligand: [{Ln(-CH 3 COO)(H 2 O) 2 (GeW 11 O 39 )} 2 ] 12− (Ln = Eu, Gd, Lu) ..................................... 135 3.B.3.1. Introduction ...................................................................................................... 135 3.B.3.2. Synthesis ........................................................................................................... 136 3.B.3.3. X-ray Crystallography ...................................................................................... 138 3.B.3.4. Results and Discussion ..................................................................................... 139 3.B.3.5. Conclusions ...................................................................................................... 143 3.B.3.6. References ........................................................................................................ 144 Chapter IV Mixed Lanthanide/d-Transition Metal Containing POMs ............................................... 146 Ring opening in the cyclic Phosphotungstate [Fe 16 O 2 (OH) 23 (H 2 O) 9 (P 8 W 49 O 189 )Ln 4 (H 2 O) 20 ] 11− ................................................................................................................................................ 146 4.1. Introduction ................................................................................................................. 146 4.2. Synthesis ...................................................................................................................... 150 vii
Page 1 and 2: Synthesis and Structural Characteri
Page 3 and 4: Amal H. Ismail Ph.D. Thesis Acknowl
Page 5 and 6: Amal H. Ismail Ph.D. Thesis Abstrac
Page 7: Amal H. Ismail Ph.D. Thesis 1.6.1 P
Page 11 and 12: Amal H. Ismail Ph.D. Thesis 5.B.2.
Page 13 and 14: Amal H. Ismail Ph.D. Thesis Figure
Page 15 and 16: Amal H. Ismail Ph.D. Thesis (pink);
Page 21 and 22: Amal H. Ismail Ph.D. Thesis List of
Page 23 and 24: Amal H. Ismail Ph.D. Thesis K 8 Cs
Page 25 and 26: Chapter 1 Introduction proposed a s
Page 27 and 28: Chapter 1 Introduction A or B. At s
Page 29 and 30: Chapter 1 Introduction c) [(H 2 )W
Page 31 and 32: Chapter 1 Introduction by protonati
Page 33 and 34: Chapter 1 Introduction structures;
Page 35 and 36: Chapter 1 Introduction mono-, di-,
Page 37 and 38: Chapter 1 Introduction Removal of t
Page 39 and 40: Chapter 1 Introduction α-[P 2 W 18
Page 41 and 42: Chapter 1 Introduction Figure 1.10
Page 43 and 44: Chapter 1 Introduction In general,
Page 45 and 46: Chapter 1 Introduction 1.6.1 Photoc
Page 47 and 48: Chapter 1 Introduction dioxygen is
Page 49 and 50: Chapter 1 Introduction 1.7 Lanthani
Page 51 and 52: Chapter 1 Introduction ligand for o
Page 53 and 54: Chapter 1 Introduction [Gd 8 As 12
Page 55 and 56: Chapter 1 Introduction Recently, we
Page 57 and 58: Chapter 1 Introduction P 2 W 16 O 5
Page 59 and 60:
Chapter 1 Introduction [7] L. C. Pa
Page 61 and 62:
Chapter 1 Introduction Malacria, C.
Page 63 and 64:
Chapter 1 Introduction [55] B. Nohr
Page 65 and 66:
Chapter 2 Experimental 2.2 Instrume
Page 67 and 68:
Chapter 2 Experimental 2.3.2 Synthe
Page 69 and 70:
Chapter 2 Experimental 2.3.8 Synthe
Page 71 and 72:
Chapter 2 Experimental 2.4 Referenc
Page 73 and 74:
Chapter 3 Published Results general
Page 75 and 76:
Chapter 3 Published Results 2.5 mL
Page 77 and 78:
Chapter 3 Published Results Na 8 [T
Page 79 and 80:
Chapter 3 Published Results matrix
Page 81 and 82:
Chapter 3 Published Results 3.A.1.4
Page 83 and 84:
Chapter 3 Published Results [H 2 W
Page 85 and 86:
Chapter 3 Published Results and one
Page 87 and 88:
Chapter 3 Published Results {W 4 }
Page 89 and 90:
Chapter 3 Published Results We also
Page 91 and 92:
Chapter 3 Published Results Figure
Page 93 and 94:
Chapter 3 Published Results We trie
Page 95 and 96:
Chapter 3 Published Results M. T. P
Page 97 and 98:
Chapter 3 Published Results 72.936(
Page 99 and 100:
Chapter 3 Published Results La, Ce,
Page 101 and 102:
Chapter 3 Published Results Na 8 Eu
Page 103 and 104:
Chapter 3 Published Results Table 3
Page 105 and 106:
Page 107 and 108:
Chapter 3 Published Results Polyani
Page 109 and 110:
Chapter 3 Published Results [LnW 10
Page 111 and 112:
Chapter 3 Published Results analogu
Page 113 and 114:
Chapter 3 Published Results We also
Page 115 and 116:
Chapter 3 Published Results example
Page 117 and 118:
Chapter 3 Published Results 1737; q
Page 119 and 120:
Chapter 3 Published Results 3.B. La
Page 121 and 122:
Chapter 3 Published Results expecte
Page 123 and 124:
Chapter 3 Published Results 3.B.1.3
Page 125 and 126:
Page 127 and 128:
Chapter 3 Published Results differe
Page 129 and 130:
Page 131 and 132:
Page 133 and 134:
Chapter 3 Published Results Acta 20
Page 135 and 136:
Chapter 3 Published Results Chem.,
Page 137 and 138:
Chapter 3 Unpublished Results bond
Page 139 and 140:
Chapter 3 Unpublished Results lanth
Page 141 and 142:
Chapter 3 Unpublished Results Na 10
Page 143 and 144:
Chapter 3 Unpublished Results Figur
Page 145 and 146:
Chapter 3 Unpublished Results 3.B.2
Page 147 and 148:
Chapter 3 Unpublished Results In po
Page 149 and 150:
Page 151 and 152:
Page 153 and 154:
Chapter 3 Unpublished Results (a) (
Page 155 and 156:
Chapter 3 Unpublished Results param
Page 157 and 158:
Chapter 3 Unpublished Results G.-F.
Page 159 and 160:
Chapter 3 Unpublished Results Here
Page 161 and 162:
Page 163 and 164:
Chapter 3 Unpublished Results This
Page 165 and 166:
Chapter 3 Unpublished Results techn
Page 167 and 168:
Page 169 and 170:
Chapter 4 Unpublished Results Chapt
Page 171 and 172:
Chapter 4 Unpublished Results The c
Page 173 and 174:
Chapter 4 Unpublished Results iron(
Page 175 and 176:
Chapter 4 Unpublished Results 4.4.
Page 177 and 178:
Page 179 and 180:
Page 181 and 182:
Chapter 4 Unpublished Results Therm
Page 183 and 184:
Chapter 4 Unpublished Results This
Page 185 and 186:
Chapter 4 Unpublished Results 4.6.
Page 187 and 188:
Chapter 4 Unpublished Results S. Ba
Page 189 and 190:
Chapter 5 Published Results Also te
Page 191 and 192:
Chapter 5 Published Results 5.A.1.3
Page 193 and 194:
Chapter 5 Published Results Table 5
Page 195 and 196:
Chapter 5 Published Results [HTe 2
Page 197 and 198:
Chapter 5 Published Results face-sh
Page 199 and 200:
Chapter 5 Published Results polymol
Page 201 and 202:
Chapter 5 Published Results Each of
Page 203 and 204:
Chapter 5 Published Results Althoug
Page 205 and 206:
Chapter 5 Published Results Polyako
Page 207 and 208:
Chapter 5 Unpublished Results 5.A.2
Page 209 and 210:
Chapter 5 Unpublished Results 610(m
Page 211 and 212:
Chapter 5 Unpublished Results 5.A.2
Page 213 and 214:
Page 215 and 216:
Chapter 5 Unpublished Results {Mo 6
Page 217 and 218:
Chapter 5 Unpublished Results compo
Page 219 and 220:
Chapter 5 Unpublished Results [3] a
Page 221 and 222:
Chapter 5 Published Results 5.B. Tr
Page 223 and 224:
Chapter 5 Published Results H 2 O)
Page 225 and 226:
Chapter 5 Published Results 5.B.3.
Page 227 and 228:
Chapter 5 Published Results Each Ke
Page 229 and 230:
Chapter 5 Published Results GeW 9 O
Page 231 and 232:
Chapter 5 Published Results the axi
Page 233 and 234:
Chapter 5 Published Results The man
Page 235 and 236:
Chapter 5 Published Results 5.B.6.
Page 237 and 238:
Chapter 5 Published Results [19] L.
Page 239:
Amal H. Ismail Ph.D. Thesis Appendi
show all

Synthesis and Structural Characterization of ... - Jacobs University

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?