Synthesis and Structural Characterization of ... - Jacobs University

Chapter 5
Published Results
Table 5.7. Selected Cu–O and Co–O bond lengths [Å] for 29 and 30, respectively a
Code 1 2
Cu(1)-O(6C) eq 1.91(1) Co(1)-O 1.97(3), 2.00(2),
Cu(1)-O(13C) eq 1.94(1)
2.02(2), 2.03(3),
Cu(1)-O(7C) eq 1.95(1)
2.04(2), 2.21(2)
Cu(1)-O(12C) eq 1.99(1)
Co(2)-O 2.02(2), 2.06(2),
Avg. Cu(1)-O eq 1.95(3)
2.06(2), 2.12(2),
2.15(2), 2.25(2)
Cu(2)-O(15C) eq 1.93(1)
Cu(2)-O(4G2) eq 1.96(1)
Cu(2)-O(4G1) eq 1.97(1)
Cu(2)-O(9C) eq 1.98(1)
Avg. Cu(2)-O eq 1.96(2)
Cu(3)-O(4G2) eq 1.97(1)
Cu(3)-O(4C) eq 1.98(1)
Cu(3)-O(10C) eq 1.98(1)
Cu(3)-O(4G1) eq 2.00(1)
Avg. Cu(3)-O eq 1.98(1)
Co(3)-O 2.06(2), 2.08(2),
2.08(3), 2.09(2),
2.09(2), 2.12(2)
Co(4)-O 2.04(3), 2.07(2),
2.08(2), 2.09(2),
2.12(3), 2.18(2)
Co(5)-O 2.03(2), 2.03(2),
2.04(3), 2.05(2),
2.08(2), 2.19(2)
Co(6)-O 2.04(2), 2.05(2),
2.06(2), 2.07(2),
2.11(2), 2.17(2)
Cu(1)-O(4G1) ax1 2.35(1)
Cu(2)-O(2C2) ax1 2.30(1)
Cu(3)-O(2C) ax1 2.31(1)
Avg. Cu-O ax1 2.32(3)
Cu(1)-O(1CU) ax2 2.55(2)
Cu(2)-O(13C) ax2 2.54(1)
Cu(3)-O(12C) ax2 2.52(1)
Avg. Cu-O ax2 2.54(2)
a Mean values are indicated in bold.
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