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Amal H. Ismail Ph.D. Thesis GeW 9 O 34 ) via a Gain of a WO 6 Unit Forming a Complete Rotated Triad. The color code is the same as in Figure 5.15. ........................................................................................................... 204 Figure 5.17. Combined ball-and-stick/polyhedral presentation of the solid-state arrangement of 30. The polyhedra represent WO 6 (red or orange) and the balls represent germanium (yellow), cobalt (green) and oxygen (red).............................................................................. 206 Figure 5.18. Polyhedral representation of the copper(II) containing 29 (left, a) and the cobalt(II) containing fragment 30a (right, b). Notice the different orientation of the rotated triad in the respective “upper” (B-β-GeW 9 O 34 ) units. ............................................................ 207 Figure 5.19. Ball-and-stick representation of the Cu 3 -core of 29 and the labeling scheme. . 208 Figure 5.20. Combined polyhedral/ball-and-stick representation of 31. The pink spheres represent Mn 2+ (31). Otherwise, the color code is the same as in Figures 5.15 – 5.19. ......... 210 xviii
Amal H. Ismail Ph.D. Thesis List of Tables Table 1.1. M … M distances (Å) of corner- and edge- sharing octahedra in POMs. ................ 4 Table 2.1. Information about the lanthanide salts products used. ........................................... 41 Table 3.1. Crystal Data and Structure Refinement for NaLa-1 – Na-10. .............................. 56 Table 4.1. Crystal Data and Structure Refinement for KLiNa-24 and KLiNa-25. .............. 151 Table 5.1. Crystal Data and Structure Refinement for (Na-26) and (Na-27)........................ 169 Table 5.2. Te–O(W) Bond Lengths (Å) for Na-26. ............................................................... 170 Table 5.3. Selected Bond Angles (/°) for Na-26. .................................................................. 170 Table 5.4. Selected W–O Bond Lenghths (Å) for Na-26. ..................................................... 170 Table 5.5. Crystal Data and Structure Refinement for Na 34 [H 2 Te 24 Mo 44 O 198 ]·84H 2 O (Na-28). ................................................................................................................................................ 187 Table 5.6. Crystal Data and Structure for K-29, K-30 and K-31. ......................................... 202 Table 5.7. Selected Cu–O and Co–O bond lengths [Å] for 29 and 30, respectively a ............ 209 xix
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