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Chapter 5 Unpublished Results novel {Mo 6 } and {Mo 10 } subunits connected by Te−O−W bridges. These hexa- and decamolybdates, {Mo 6 } and {Mo 10 }, subunits have not been reported before. The rare existence of structurally characterized of d-transition metals containing molybdotellurates(IV) provides an impetus to try to prepare new species of molybdotellurates(IV). Hence, we tried to incorporate d-transition metal ions (Mn 2+ , Fe 3+ , Co 2+ , Ni 2+ , Cu 2+ , Zn 2+ , and Pd 2+ ) in polyanion 1 using different synthetic pathways. So far, we could not identify the crystalline materials obtained by using single-crystal X-ray diffraction and this will be the scope of further studies. 5.A.2.6. References [1] a) M. T. Pope in Heteropoly and Isopoly Oxometalates, Springer-Verlag, Berlin, 1983; b) M. T. Pope, A. Müller, Angew. Chem., 1991, 103, 56, Angew. Chem., Int. Ed. Engl. 1991, 30, 34; c) M. T. Pope, A. Müller in Polyoxometalates: From Platonic Solids to Anti- Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer: Dordrecht, The Netherlands, 1994; d) A. Müller, H. Reuter, S. Dillinger, Angew. Chem., 1995, 107, 2505, Angew. Chem., Int. Ed. Engl. 1995, 34, 2328; e) C. Hill in Polyoxometalates: Chemical Reviews, 1998 (special thematic issue on polyoxometalates); f) M. T. Pope, A. Müller in Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications (Eds.: M. T. Pope, A. Müller), Kluwer: Dordrecht, The Netherlands, 2001; g) T. Yamase, M. T. Pope in Polyoxometalate Chemistry for Nano- Composite Design (Eds.: T. Yamase, M. T. Pope), Kluwer: Dordrecht, The Netherlands, 2002; h) D.-L. Long, E. Burkholder, L. Cronin, Chem. Soc. Rev. 2007, 36, 101; i) D.-L. Long, R. Tsunashima, L. Cronin, Angew. Chem. 2010, 122, 1780, Angew. Chem. Int. Ed. 2010, 49, 1736. [2] a) J. S. Anderson, Nature 1937, 140, 850; b) H. T. Jr. Evans, J. Am. Chem. Soc. 1948, 70, 1291; c) H. T. Jr. Evans, Acta. Cryst. 1974, B30, 2095. 195
Chapter 5 Unpublished Results [3] a) K. J. Schmidt, G. J. Schrobilgen, J. F. Sawyer, Acta Crystallogr. 1986, C42, 1115; b) A. Sagasaki, Y. Sasaki, Bull. Chem. Soc. Jpn 1987, 60, 763; c) T. Ozeki, A. Yagasaki, H. Ichida, Y. Sasaki, Polyhedron 1988, 7, 1131; d) M. S. Grigorev, Yu. T. Struchkov, A. M. Feddoseev, A. B. Yusov, A. I. Yanovskii, Z. Neorg. Khim. 1992, 37, 2507; e) C. Robl, M. Frost, Z. Anorg. Allg. Chem. 1993, 619, 1834; f) C. Robl, M. Frost, Z. Anorg. Allg. Chem. 1993, 619, 1137; g) C. Robl, M. Frost, Z. Anorg. Allg. Chem. 1993, 619, 1132; h) C. Robl, M. Frost, Z. Anorg. Allg. Chem. 1993, 619, 1624; i) C. Robl, M. Frost, Z. Naturforsch. B, 1993, 48, 404; j) P. A. Lorenzo-Luis, P. Martin- P. Zarza, R. Gili, Saez-Puche, J. Jimenez-Jimenez, E. Rodriguez- Castellon, C. Ruiz-Perez, J. Gonzalez-Platas, X. Solans, Eur. Solid State Inorg. Chem. 1997, 34, 1271; j) D. Drewes, E. M. Limanski, B. Krebs, Dalton, 2004, 2087; k) D. Drewes, E. M. Limanski, B. KrebsEur. Inorg. Chem. 2004, 4849; l) D. Drewes, B. Krebs, Z. Anorg. Allg. Chem. 2005, 631, 2591; m) I. A. Charushnikova, A. B. Yusov, A. M. Feddoseev, I. N. Polyakova, Z. Neorg. Khim. 2004, 49, 1481; n) I. A. Charushnikova, A. M. Feddoseev, A. B. Yusov, C. D. Auwer, Crystallogr. Reports 2005, 50, 191; o) G. Bo, L. Shu-Xia, X. Lin-Hua, Y. Miao, Z. Chung-Dan, S. Chung-Yan, C. Hai-Yan, J. Solid State Chem. 2006, 179, 1689. [4] a) P. A. Lorenz-Luis, P. Martin-Zarza, A. Sanchez, M. Hernandez-Molina, X. Solans, P. Gili, Inorg. Chim. Acta 1998, 277, 139; b) P. Gili, P. A. Lorenz-Luis, P. Martin-Zarza, S. Dominguez, A. Sanchez, J. M. Arrieta, E. Rodriguez-Castellon, J. Jimenez-Jimenez, C. Ruiz- Perez, M. Hernandez-Molina, X. Solans, Transiton Met. Chem. 1999, 24, 141; c) V. Balraj, K. Vidyasagar, Inorg. Chem. 1999, 38, 1394; d) F. Wang, S.-X. Liu, C.-L. Wang, R.-G. Cao, J.-F. Cao, Acta Crystallogr. 2007, E63, m1708; e) Z.-H. Xu, P.-X. Xi, F.-J. Chen, Z.-Z. Zeng, Analytical Sciences 2007, 23, x235. [5] a) E. S. Ganelina, Russ. J. Inorg. Chem. 1962, 7, 812; b) E. S. Ganelina, N. I. Nerevyatkina, Russ. J. Inorg. Chem. 1965, 10, 483; c) R. Ripan, N. Calu, Stud.Univ. Babes- Bolyai, Chem. 1965, 10, 135. 196
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