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Assessment of Conversion Technologies for Bioalcohol Fuel ...

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Technology Characteristics–The Paszner ACOS Process is a hydrolysis process<br />

described as “a unique solvent pulping variant in which the chemistry in the reactor<br />

has been modified in a manner that total (100%) dissolution <strong>of</strong> all biomass<br />

components becomes possible in a single step, achieved by the use <strong>of</strong> a benign<br />

congruent solvent system”. The proprietary solvent chemistry brings about<br />

simultaneous hydrolysis <strong>of</strong> both carbohydrates and lignin and prevents unwanted<br />

byproducts (such as furfurals). 100 percent solvent recycling is said to be achieved,<br />

with no wastewater disposal requirements. No feedstock pre-treatment is required<br />

other than chipping or hammer-milling. The process is intended to be a simple, lowcost,<br />

low-temperature, short reaction time process applicable to any lignocellulosic<br />

feedstocks, including all coniferous and deciduous tree and shrub species and their<br />

barks, agricultural crop residues and grasses, municipal cellulosic solid wastes,<br />

various manures and paper mill sludge. The process is said to be amenable to smallscale<br />

applications.<br />

Development Status–The Paszner ACOS process has been under development <strong>for</strong><br />

28 years, with various bench-scale and pilot-scale testing conducted. This<br />

development work has received limited funding support from Energy Mines and<br />

Resources Canada, a Canadian government agency. This testing is said to have<br />

involved some 35 lignocellulosic species <strong>of</strong> feedstocks. An engineering feasibility<br />

study was completed in 1994. The most recent physical testing phase <strong>of</strong> the process<br />

was apparently completed in 2001, and funding <strong>for</strong> further phases <strong>of</strong> development has<br />

yet to be obtained. Paszner delivered a presentation on its technology at the USDOE<br />

Ethanol Workshop held April 2003 in Sacramento.<br />

Future Development Plans–Paszner <strong>Technologies</strong> has identified and developed<br />

preliminary plans <strong>for</strong> projects applying its plans at numerous sites in Canada, the U.S.,<br />

and various other countries. However, none <strong>of</strong> these projects is known to be moving<br />

<strong>for</strong>ward at this time, with Paszner continuing to pursue funding <strong>for</strong> continued<br />

development <strong>of</strong> its process and to seek potential partners <strong>for</strong> its commercialization.<br />

Petrobras, Rio de Janeiro, Brazil<br />

Organizational Background–Petrobras was <strong>for</strong>med in 1953 when Brazilian<br />

President Vargas signed a law establishing the monopoly <strong>of</strong> the Brazilian federal<br />

government over the activities <strong>of</strong> the oil industry in the country and authorizing the<br />

creation <strong>of</strong> Petróleo Brasileiro S.A. Petrobras as the state company to be the executor<br />

<strong>of</strong> the monopoly. Today Petrobras is the world’s14th largest oil company, and<br />

operates as a semi-public corporation, with activities in at least seven countries<br />

besides Brazil. Petrobras has been instrumental in the development <strong>of</strong> Brazil’s<br />

ethanol fuel program (Proalcool) since its inception in the 1970s. Recently, Petrobras<br />

announced that the company is developing a biomass-to-ethanol process at its<br />

corporate research and development center.<br />

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