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Cleaner Technology Transfer to the Polish Textile ... - Miljøstyrelsen

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Detergents and<br />

complexing agents<br />

Figure 5.<br />

Effect of detergent and<br />

complexing agents on<br />

rinsing, 95°C.<br />

Figure 6.<br />

Effect of detergent/complexing<br />

agents on rinsing, 105°C.<br />

70<br />

The dye-stuff content in <strong>the</strong> rinse water versus time, depending on temperature<br />

in <strong>the</strong> rinse, is plotted out in figure 4. By raising <strong>the</strong> temperature from 75°C <strong>to</strong><br />

95°C it is possible <strong>to</strong> double <strong>the</strong> dye-stuff content in <strong>the</strong> rinse water in <strong>the</strong><br />

same process time. At 75°C and 95°C an equilibrium is reached after approx.<br />

30 minutes process time. The curve at 105°C indicates that <strong>the</strong> dye-stuff is<br />

washed off <strong>the</strong> textile, and that no equilibrium is reached.<br />

Unlike <strong>the</strong> temperature, detergents and complexing agents have none or at<br />

worst case have an impeding effect on <strong>the</strong> dye-stuff hydrolysate rinse. In<br />

figures 5 and 6, <strong>the</strong> effect of different auxiliary agents on rinsing is outlined.<br />

The dye-stuff content of <strong>the</strong> rinse water versus time, depending on different<br />

doses of auxiliary agents in proportion <strong>to</strong> normal dose, is plotted out in figures<br />

5 and 6. The heavy line in figure 5 indicates <strong>the</strong> temperature during heating:<br />

20 minutes heating from 10°C <strong>to</strong> 95°C, and subsequently constant at 95°C.<br />

The curve indicates an exponential coherence between temperature and dyestuff<br />

content in <strong>the</strong> rinse water up <strong>to</strong> when <strong>the</strong> constant temperature and equilibrium<br />

is reached. In figure 5 <strong>the</strong>re seems <strong>to</strong> be no difference between using<br />

normal dose, half dose, quarter dose, or no auxiliary agent.<br />

In figure 6 <strong>the</strong>re is no heating, temperature constant 105° C. The best result is<br />

obtained by no use of auxiliary agent.

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