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NASA Scientific and Technical Aerospace Reports

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20040074206 Arizona Univ., Tucson, AZ, USA<br />

The Abundance <strong>and</strong> Isotopic Composition of Hg in Extraterrestrial Materials<br />

Lauretta, D. S.; [2004]; 5 pp.; In English<br />

Contract(s)/Grant(s): NAG5-11355; No Copyright; Avail: CASI; A01, Hardcopy<br />

During the past three year grant period we made excellent progress in our study of the abundances <strong>and</strong> isotopic<br />

compositions of Hg <strong>and</strong> other volatile trace elements in extraterrestrial materials. As part of my startup package I received<br />

funds to construct a state-of-the-art experimental facility to study gas-solid reaction kinetics. Much of our effort was spent<br />

developing the methodology to measure the abundance <strong>and</strong> isotopic composition of Hg at ultratrace levels in solid materials.<br />

In our first study, the abundance <strong>and</strong> isotopic composition of Hg was determined in bulk samples of the Murchison (CM) <strong>and</strong><br />

Allende (CV) carbonaceous chondrites. We have continued our study of mercury in primitive meteorites <strong>and</strong> exp<strong>and</strong>ed the<br />

suite of meteorites to include other members of the CM <strong>and</strong> CV chondrite group as well as CI <strong>and</strong> CO chondrites. Samples<br />

of the CI chondrite Orgueil, the CM chondrites Murray, Nogoya, <strong>and</strong> Cold Bokkeveld, the CO chondrites Kainsaz, Omans,<br />

<strong>and</strong> Isna, <strong>and</strong> the CV chondrites Vigarano, Mokoia, <strong>and</strong> Grosnaja were tested. We have developed a thermal analysis ICP-MS<br />

technique <strong>and</strong> applied it to the study of a suite of thermally labile elements (Zn, As, Se, Cd, In, Sn, Sb, Te, Hg, Au, Tl, Pb,<br />

<strong>and</strong> Bi) in geologic materials as well.<br />

Derived from text<br />

Mercury (Metal); Meteoritic Composition; Abundance; Isotope Ratios<br />

20040074237 <strong>NASA</strong> Goddard Space Flight Center, Greenbelt, MD, USA<br />

Feasibility of Sensing Tropospheric Ozone with MODIS 9.6 Micron Observations<br />

Prabhakara, C.; Iacovazzi, R., Jr.; Moon-Yoo, Jung; [2004]; 2 pp.; In English; AGU Fall 2003 Meeting, 8-12 Dec. 2003, San<br />

Francisco, CA, USA; No Copyright; Avail: Other Sources; Abstract Only<br />

With the infrared observations made by the Moderate Resolution Imaging Spectrometer (MODIS) on board the<br />

EOS-Aqua satellite, which include the 9.73 micron channel, a method is developed to deduce horizontal patterns of<br />

tropospheric ozone in cloud free conditions on a scale of about 100 km. It is assumed that on such small scale, at a given<br />

instant, horizontal changes in stratospheric ozone are small compared to that in the troposphere. From theoretical simulations<br />

it is found that uncertainties in the l<strong>and</strong> surface emissivity <strong>and</strong> the vertical thermal stratification in the troposphere can lead<br />

to significant errors in the inferred tropospheric ozone. Because of this reason in order to derive horizontal patterns of<br />

tropospheric ozone in a given geographic area a tuning of this method is necessary with the help of a few dependent cases.<br />

After tuning, this method is applied to independent cases of MODIS data taken over Los Angeles basin in cloud free conditions<br />

to derive horizontal distribution of ozone in the troposphere. Preliminary results indicate that the derived patterns of ozone<br />

resemble crudely the patterns of surface ozone reported by EPA.<br />

Author<br />

MODIS (Radiometry); Ozone; Troposphere; Earth Surface; Satellite Observation; Detection<br />

92<br />

SOLAR PHYSICS<br />

Includes solar activity, solar flares, solar radiation <strong>and</strong> sunspots. For related information see 93 Space Radiation.<br />

20040068144 Stanford Univ., CA, USA<br />

Simulation of Multiple Shocks in the Solar Atmosphere using a High-Order Shock-Capturing Scheme<br />

Bryson, Steve; Kosovichev, A.; Levy, Doron; January 2004; 1 pp.; In English; SIAM 2004 Annual Meeting, 12 - 16 Jul. 2004,<br />

Portl<strong>and</strong>, OR, USA; No Copyright; Avail: Other Sources; Abstract Only<br />

We present a simulation of shock phenomena in the solar atmosphere using high-order shock capturing central-upwind<br />

schemes, based on the Euler equation in gravity. These simulations use observation-based initial conditions, with results<br />

matching observation. Various difficulties are highlighted, including very high gradients in the initial data, multiple scales, <strong>and</strong><br />

initialization in hydrostatic equilibrium. We focus on the design of algorithms to address these problems, as well as the<br />

interaction with observational data.<br />

Author<br />

Solar Atmosphere; Computerized Simulation; Shock Waves; Upwind Schemes (Mathematics)<br />

328

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