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Timing, hosts and locations of (grouped) events of NanoImpactNet

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NanoSafetyCluster - Compendium 2012<br />

<strong>of</strong> predictive models for the impact <strong>of</strong> nanomaterials on human<br />

health <strong>and</strong> environment. These studies will include the LCA analysis<br />

<strong>of</strong> nanomaterials included in polymeric host to determine their<br />

global environmental impact. Additionally, three recycling<br />

strategies will be considered in order to give solutions for the<br />

recovery <strong>of</strong> innocuous nanomaterials toxic. For this purpose,<br />

exhaustive evaluations for the selection <strong>of</strong> adequate dissolving <strong>and</strong><br />

extraction methods to separate the nanomaterials from the<br />

polymeric matrix will be carried out. The strategies proposed for<br />

the recycling process will be the following: The direct mechanical<br />

recycling <strong>of</strong> nanocomposites, the recycling <strong>of</strong> nanomaterials <strong>and</strong><br />

polymers obtained by novel chemical separation techniques based<br />

on nan<strong>of</strong>iltration using tailored nan<strong>of</strong>iber-based filters, <strong>and</strong> the<br />

recycling <strong>of</strong> polymers <strong>and</strong> immobilization <strong>of</strong> toxic nanomaterials in<br />

inert matrices.<br />

1 Concept <strong>and</strong> Objectives<br />

NANOPOLYTOX is a small-medium size collaborative project from<br />

the FP7 within the topic NMP-2009-1.3-1: Activities towards the<br />

development <strong>of</strong> appropriate solutions for the use, recycling <strong>and</strong>/or<br />

final treatment <strong>of</strong> nanotechnology-based products (Joint call with<br />

Theme 6: Environment including Climate Change).<br />

1.1 Background<br />

The global industry is moving forward taking advantages <strong>of</strong> the<br />

new opportunities <strong>and</strong> prospects <strong>of</strong>fered by nanotechnology;<br />

therefore it is necessary that these developments take place in a<br />

safe <strong>and</strong> sustainable manner. The increasing use <strong>of</strong> nanomaterials<br />

in consumer products has raised concerns over their safety to<br />

human health <strong>and</strong> the environment. Currently, there are major<br />

gaps regarding to the health <strong>and</strong> environment risks presented by<br />

the nanomaterials. During the cycle life <strong>of</strong> a nanomaterial, workers<br />

<strong>and</strong> consumers are exposed to these materials. While workers are<br />

exposed during the process <strong>of</strong> production <strong>and</strong> the process <strong>of</strong><br />

recycling or disposal <strong>of</strong> the industrial nanoproducts, consumers are<br />

exposed during the use <strong>of</strong> the products. Moreover, sooner or later<br />

the nanomaterials are free to enter the environment. Therefore, an<br />

exhaustive characterization <strong>and</strong> toxicity evaluation at different<br />

stages <strong>of</strong> the life cycle <strong>of</strong> nanomaterials used in industrial<br />

production is required. NanoPolyTox project proposes to study the<br />

evolution <strong>of</strong> nanomaterials physico-chemical <strong>and</strong> toxicological<br />

properties during their life cycle to evaluate their global<br />

environmental impact. Furthermore, NanoPolyTox studies will<br />

include the development <strong>of</strong> innovative strategies for the recycling<br />

<strong>and</strong> disposal <strong>of</strong> nanomaterials that are included in polymeric<br />

matrices.<br />

1.2 Objectives<br />

The main goal <strong>of</strong> NanoPolyTox is to improve the underst<strong>and</strong>ing <strong>of</strong><br />

the potential environmental/health impact <strong>of</strong> nanotechnologybased<br />

products over their life cycle. Gathering <strong>and</strong> generating data<br />

on the possible impact on human health <strong>and</strong>/or the environmental<br />

impact derived from the use, re-use, recycling <strong>and</strong>/or final<br />

treatment <strong>and</strong> disposal <strong>of</strong> nanotechnology-based products<br />

containing engineered nanoparticles. The project is focused on<br />

after-production stages <strong>and</strong> will address the following issues for<br />

the products considered: Physical <strong>and</strong> chemical characterization,<br />

hazard characterization (human toxicity <strong>and</strong> ecotoxicity),<br />

environmental <strong>and</strong> biological fate, transformation, <strong>and</strong> destiny <strong>of</strong><br />

nanoparticles. Additionally, this project will provide, at laboratory<br />

scale, technological solutions for recycling <strong>and</strong> final treatment <strong>of</strong><br />

nanotechnology-based products.<br />

1.2.1 Specific Objectives<br />

- The preparation <strong>of</strong> nanomaterials from three different<br />

families (carbon nanotubes, nanoclays <strong>and</strong> metal oxide<br />

nanoparticles) including adequate tailoring functionalities<br />

for their inclusion in three selected polymeric <strong>hosts</strong><br />

widely used in several industrial sectors<br />

- Generation <strong>of</strong> nanocomposite samples by processing in<br />

double screw extruders <strong>and</strong> further injection in test<br />

specimens<br />

- Weathering <strong>of</strong> the raw nanomaterials <strong>and</strong> the<br />

nanocomposite test specimens in climatic chambers<br />

- Fully characterization (physical <strong>and</strong> chemical properties)<br />

<strong>of</strong> all the samples (raw nanomaterials <strong>and</strong><br />

nanocomposites) during their life cycle<br />

- Collection <strong>of</strong> toxicological data (in vitro <strong>and</strong> in vivo<br />

human toxicity <strong>and</strong> ecotoxicity) for selected samples to<br />

evaluate the risks associated with their manufacturing,<br />

use, recycling <strong>and</strong> disposal<br />

- Development <strong>of</strong> predictive models based on the data<br />

obtained for the evolution <strong>of</strong> the physico-chemical <strong>and</strong><br />

toxicological properties <strong>of</strong> the nanomaterials along their<br />

life cycle<br />

- Detection <strong>and</strong> quantification <strong>of</strong> possible migrations<br />

<strong>and</strong>/or releases <strong>of</strong> the nan<strong>of</strong>illers from the polymeric<br />

matrices, establishing a relationship between weathering<br />

cycles <strong>and</strong> migration/release <strong>of</strong> nanomaterials<br />

- Mechanical <strong>and</strong> chemical recycling for innocuous <strong>and</strong><br />

toxic nanomaterials including the development <strong>of</strong> a new,<br />

efficient <strong>and</strong> cost effective chemical recycling technology<br />

based on specific nan<strong>of</strong>iber filters<br />

- Development <strong>of</strong> new solutions for the disposal <strong>of</strong> toxic<br />

nanomaterials based on the inclusion <strong>of</strong> specific<br />

nan<strong>of</strong>ibers filters containing the toxic nanomaterials, into<br />

xerogel matrices by sol-gel processes <strong>and</strong> sintering<br />

- Evaluation <strong>of</strong> the global environmental impact <strong>of</strong><br />

nanomaterials that are highly used in many industrial<br />

sectors during their life cycle by LCA analysis specifically<br />

complemented with the data obtained during this project<br />

<strong>and</strong> other European projects related to nanosafety<br />

NanoPolyTox will provide important information on a general<br />

concern regarding the degradability <strong>of</strong> polymer nanocomposites<br />

<strong>and</strong> their direct impact on human health <strong>and</strong> environment. It is<br />

expected that these results can prevent or minimize the exposure<br />

<strong>of</strong> workers <strong>and</strong> consumers, <strong>and</strong> releases to environment <strong>of</strong><br />

hazardous nanomaterials.<br />

160 Compendium <strong>of</strong> Projects in the European NanoSafety Cluster

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