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Chapter III CHN Analysis, FT IR …..<br />

Figure: 3.16 Powder x – ray diffraction pattern for DL – methionine doped KDP<br />

crystals.<br />

From figures (3.14 to 3.16) one can notice that all the figures exhibit<br />

almost the single phase nature. The doping of amino acids does not bring<br />

large distortion in KDP crystal and it allows retaining almost the single phase<br />

nature. In all doped samples, very little variation in the unit cell parameters is<br />

observed compare to pure KDP crystal, this may be due to larger amino acid<br />

molecules have adjusted inside interstitial voids instead of replacement of<br />

KDP molecule at any lattice point, the small variation in cell parameters can<br />

also be attributed to small strain on lattice.<br />

153

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