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Chapter I Brief Introduction...<br />

memory [28], two photons scanning microscope [29] and demonstrated the<br />

3D micro-modification and tera bit /cm 3 3D optical data storage.<br />

The nonlinear optical phenomenon of SHG has intrinsic sensitivity to<br />

the voltage across a biological membrane. The second order NLO process<br />

has been used to monitor membrane voltage by Bouevitch et al [30].<br />

1.7 Materials for Nonlinear Optics<br />

As the technological importance and applications of NLO materials is<br />

continuously increasing the quest is going on to develop the most suitable<br />

NLO material. The understanding of the nonlinear polarization mechanisms<br />

and their relation to the structural characteristics of the materials has been<br />

considerably improved. The new development of techniques for the<br />

fabrication and growth of artificial materials has dramatically contributed to<br />

this evolution. The aim is to develop materials presenting large nonlinearities,<br />

at the same time, not only all the technological requirements for applications<br />

such as, wide transparency range, fast response and high damage threshold,<br />

but also satisfying the processability, adaptability and interfacing with other<br />

materials.<br />

Advances in the development of NLO materials can be divided into<br />

three different areas.<br />

(i) Discovery of new NLO materials<br />

(ii) Growth of promising NLO crystals<br />

(iii) Improving the characteristics of NLO crystals<br />

From materials point of view, the NLO materials can be broadly<br />

classified in three different categories as, inorganic, organic and semi-organic<br />

or metalorganic materials. Inorganic and organic possess their own set of<br />

19

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