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Chapter I Brief Introduction...<br />

1.12 Aim of the present study<br />

The advantage of NLO materials in lasers and electro-optics became<br />

clear in the early days of lasers, and enabled the expansion of their limited<br />

spectral regime. Today, there is a large number of nonlinear optical materials<br />

available for specific required wavelengths, with various damage threshold<br />

values and with various optical characteristics. The full characterization of<br />

NLO materials will involve proper documentation of these parameters.<br />

Techniques for measurement of these parameters are numerous and can<br />

readily be found in the literature.<br />

Among organic crystals of NLO applications, amino acids exhibit specific<br />

features of interest [133] such as:<br />

Molecular chirality, which secures non-centro (acentric) symmetric<br />

crystallographic structure,<br />

Absence of strongly conjugated bonds, which leads to wide<br />

transparency ranges in the visible and UV spectral regions<br />

Zwitter ionic nature of the molecule, which favors crystal hardness.<br />

Looking at the properties of various amino acids, three amino acids, viz,<br />

L-listidine, L-threonine and DL-methionine have been selected for doping in<br />

KDP crystals. The aim of the present study is to increase the SHG efficiency<br />

and optical transparency of KDP crystals by amino acids doping without giving<br />

much sacrifice to other properties. This will help further to develop crystals of<br />

better qualities for device applications. In order to investigate that, the present<br />

author has focused his attention on of the following aspects.<br />

39

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