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Chapter I Brief Introduction...<br />

fashion than that can be done in electronics. Another advantage is that light<br />

being made up of uncharged photos, which do not interact with one another<br />

as readily as electrons do. The role of NLO materials have becomes<br />

extremely important. Such materials can change the color of light and<br />

modulate its properties. Several optical computers require efficient nonlinear<br />

optical materials for their operations. Several organic materials have been<br />

explored for their use in optical devices, having high nonlinearities, flexibility of<br />

molecular design and damage resistance to optical radiation. A novel photo-<br />

deposition process for film on to quartz or glass surface has been carried out<br />

in NASA which enabled polydiacetylene film deposition having large<br />

nonlinearities and fast response time less than 120 fs (1fs=10 -15 s). The optical<br />

AND and NAND gates have been demonstrated [111].<br />

Mardar [27], in his well known article on Organic NLO materials.<br />

“Where we have been and where we are going”, has given details of future<br />

developments. It is expected that the electro-optic coefficient value of 500<br />

pm/V would be achieved in poled polymers, which may enable their use for<br />

various applications such as, efficient terahertz frequency generation<br />

facilitating image process for medical and security purpose. It is expected that<br />

all optical signal processing will be possible based on third-order NLO<br />

materials. The rapid development of two-photon micro-fabrication will help to<br />

push the limits of achievable resolution below 100 nm. The application of<br />

organic NLO materials for biomedical application including imaging, sensing,<br />

treatment and tissue engineering will be envisaged. The combination of<br />

efficient organic NLO materials with nano-structured metal clusters will<br />

provide dramatically enhanced NLO effects through surface plasmons.<br />

36

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