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Chapter IV Thermal Studies of …..
log 10 [{1 - (1- ) 1 - n } / { T 2 .(1- n)}]
log 10 [{1 - (1- ) 1 - n } / { T 2 .(1- n)}]
log 10 [{1 - (1- ) 1 - n } / { T 2 .(1- n)}]
6.4 KDP + 0.3 L-mitheonine
6.2
6.0
5.8
5.6
5.4
0.00204 0.00210 0.00216
1/T (K -1 )
6.2 KDP + 0.4 L-mitheonine
6.0
5.8
5.6
5.4
0.00196 0.00203 0.00210
6.0
5.8
5.6
5.4
1/T (K -1 )
KDP + 0.5 L-mitheonine
5.2
0.00192 0.00198 0.00204 0.00210
1/T (K -1 )
Figure: 4.11 The plots for C-R relation for different amount of DL-methionine doped KDP
crystals.
Table (4.2) compiles the values of activation energy, frequency factor and
order of reaction. The values of activation energy and frequency factor
decrease as the amount of amino acid doping increases. The activation
energy is considered as a barrier to be surmounted for reactant to combine to
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