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Chapter I Brief Introduction...<br />

dispersion and group velocity imposed in gratings, these structures also offer<br />

new opportunities for generating soliton like effects over the short length<br />

scales at low powers and short pulses.<br />

Nanophotonics is again one prominent developing branch [108,109].<br />

The application of nonlinear optics in photonic nanowires is discussed by<br />

Foster et al [110]. Nanowaveguides, fabricated from glasses or<br />

semiconductors, provide the maximum confinement of light for index guiding<br />

structures enabling large enhancement of nonlinear interactions and group<br />

velocity dispersion engineering. The combination of these two properties<br />

make photonic nano wires ideally suited for many nonlinear applications such<br />

as the generation of single cycle pulse and optical processing with sub-mW<br />

powers.<br />

Apart from the growth of organic crystals, the inclusion complexes,<br />

mono and multilayered assemblies for example, Langmuir-Blodgett films and<br />

poled polymers are considered. In the inclusion complexes, for instance, -<br />

cyclodextric (-CD), a cyclic polysaccharide that crystallizes with spatial voids<br />

in its three dimensional structure and the guest molecules such as N- methyl-<br />

4 nitroaniline can be incorporated without destroying the crystal structure of<br />

the host -CD. Due to the polar symmetry of -CD crystal, a net polar order of<br />

the guest molecule is achieved [14]. For creating a polar material, the<br />

approach of self-assembled mono and multilayer structures, for example,<br />

Langmuir-Blodgett films have been developed. In this method the transfer of<br />

monolayer films of an amphiphiles containing -chromophores from an air-<br />

water interface to a solid substrate is carried out. This process can be<br />

34

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