Full set of Notes with Fill-Ins - San Jose State University

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Chem 155 Unit 6 Page 128 of 316Resolution DefinedResolution is defined as R ≡ λ / ΔλResolution is the ability to just separate two adjacentspectral lines. For example, consider the output of amonochromator with 0.1 nm versus 1 nm resolution.In this case two purely monochromatic sources of 501and 502 nm are focused into the entrance slit.Grating Resolution Limted ThroughputLow resolution(1 nm)Light throughput500 500.5 501 501.5 502 502.5 503Wavelength / nmR=0.1 nmR=1 nm x 10Note that the low resolution case has much lowerintensity as well.Page 128 of 316
Chem 155 Unit 6 Page 129 of 316Grating ResolutionResolution may be limited by the size of the grating aswell. The grating resolution, R, is given by:R ≡ λ / Δλ = nNn =N =Diffraction orderNumber of grooves of the grating that areilluminatedGrating resolution imposes a kind of effectivebandwidth limitation Δλ just like the Δλ EFF definedabovePlease note these three things:1. Both grating resolution and effective bandwithdefine a minimum resolvable Δλ for themonochromator.2. A given monochromator will be limited by theworse of the two parameters.3. This is usually Δλ EFFPage 129 of 316
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