Full set of Notes with Fill-Ins - San Jose State University

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Chem 155 Unit 16 290 of 3161.1.68 Quadrupole Mass Filters:10,000Resolution up to:Masses limted to:< 4000 AMUStable trajectory is a function of:AC amplitudeDC fieldA given AC amplitude + DC fieldyields a stable trajectory for one:Like E and B sectors this is a:One ‘scans’ m/z:M/zmass filterscanning mode (seeone at a time)Page 290 of 316
Chem 155 Unit 16 291 of 3161.1.69 Time of Flight (TOF):Ion kinetic energy E = zV PULSEBut kinetic energy E =½mv 2So, a drift length L gives a the “flight” time t F =L/vSolve for m/Z as a function of V PULSE and distance L:E = zV PULSE = ½mv 2 = ½m(L/t F ) 22V PULSE (t F /L) 2 = m/z = (2V/L²) t F2So, one measures ion m/z by measuring the ion’sArrival time at the detector: t FPage 291 of 316
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