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Chem 155 Unit 15 268 of 316Also note that:Purely centro-symmetric modes are only Ramanactive, but IR inactive.Most modes are both Raman and IR allowed.Many allowed modes may be too weak to detect ineither Raman or IR or both.Intensity distributions between Raman and IR oftendiffer substantially.Page 268 of 316
Chem 155 Unit 15 269 of 316Some general points regarding Raman:Pro: Raman uses visible light:OpticsSolventsBiological samplesImaging with Raman has better spatial resolutionbecause of the shorter wavelengths used.Microscopes can be used in ‘Raman microprobe’mode.Silver and gold particles or rough surfaces can verystrongly enhance Raman scattering.Different vibrational modes can be seen (e.g.centrosymmetric)1ν vib ⋅2πkμVery low frequency modes are accessible (e.g.inorganics):Depolarization ratio can distinguish betweensymmetric and asymmetric stretches.Page 269 of 316
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