Full set of Notes with Fill-Ins - San Jose State University

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Chem 155 Unit 15 260 of 316A Raman scattering experiment:Scattered BeamHigh resolutionmonochromator /interferometer +sensitive detectorLaserTransmitted BeamIncident BeamThe sample may be aconcentrated solution, a neatliquid analyte, a transparentsolid or a surface.Raman is not usuallyused for dilutesolutions.If the laser is, e.g. a HeNe laser (λ=632.8 nm), most of the scatteredradiation will be:632.8 15803 cm -1nm or 1/(632.8x10 -7 cm) =This scattered radiation is monochromatic, and is known in the spectrumas the:Rayleigh LinePage 260 of 316
Chem 155 Unit 15 261 of 316What a Raman Spectrum Looks LikeIdentify in the following:1. The Rayleigh peak.2. The elastically scattered light peaks.3. The inelastically scattered light peaks.4. The Stokes peaks.5. The anti-Stokes peaks.6. Rationalize the relative intensity differencesbetween the Stokes and anti-Stokes peaks..Hypothetical Raman Scattering Spectrum .Light Power400 425 450 475 500 525 550 575 600 625 650Wavelength / nmPage 261 of 316
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