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Full set of Notes with Fill-Ins - San Jose State University

Full set of Notes with Fill-Ins - San Jose State University

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Chem 155 Unit 14 249 <strong>of</strong> 316Solvents for IR spectroscopy:Handling <strong>of</strong> neat (pure – no solvent) liquids:<strong>San</strong>dwich your sample between IR-transparentplates: e.g. NaCl:Q. If your sample is 10 microns thick, and theconcentration <strong>of</strong> molecules in the neat sample is10 M, and a typical band gives an absorbance <strong>of</strong> 0.1a. what is ε?A=εbC ε = A/bC = 0.1/0.001*10ε = 10b. why can’t you use a 1-cm pathlength NaCl cuvette?Page 249 <strong>of</strong> 316A=εbC = 10*1*10 = 100T=10 -100 = 0.00000000000000…….01

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