Full set of Notes with Fill-Ins - San Jose State University

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Chem 155 Unit 16 284 of 3161.1.64 Matrix Assisted Laser Desorption-Ionization(MALDI):o ‘Soft ‘o Pulsed introduction of solidso Large molecules – proteins / biomoleculeso Gives predominance of M +sample invacuumchamberproteins inmatrixmatrixionizessupersonicexpansionPage 284 of 316
Chem 155 Unit 16 285 of 3161.1.65 Electrospray Ionization (ESI):o ‘Soft ‘o Continuous introduction of solidso Large molecules – proteins / biomoleculeso Gives many different charge states: M + , M +2 , M +3 ,M +4 , M +5 etc.What happens when charged droplets dry out?Page 285 of 316
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Full set of Notes with Fill-Ins - San Jose State University

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