Full set of Notes with Fill-Ins - San Jose State University

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Chem. 155 Unit 4 Page 90 of 316Optical SourcesCostTrade Off$$ VUV Only?$$ Short Lifetimes$$ Popular UV-source – usedwith W-Halogen for UV-Vis$ W-HalogenVisible only, long lifetimes$$ NIR and IR Only$ IR only$ IR Only$$ Low intensity, limited λ’s$$- $$$$ Exellent Intensity, limitedλ’s$ - $$ very high resolution, poordynamic range$$-$$$ PMT v. fast, v.v. sensitive,delicate, limited in IR$-$$ low sensitvity, limited in IRbut cheap$ - $$$ sensitive and fast, muchtougher than PMT$$-$$$$ v. sensitive, slow, tough,$$-$$$ detector of choice most IRMore exotic ‘energy detectors’ – don’tknow much about thesePage 90 of 316
Chem. 155 Unit 4 Page 91 of 316Continuum Sources of Light:Broadband or White Light SourcesAlso called:1. Simplest Design:Blackbody Sourcesa. Tungstenb. Quartz-Tungsten-Halogenc. Nernst GlowerVisible / Near IR / IRIR / Far IR2. Gas Emission Designs:a. H 2 / D 2UV OnlyH 2 + e - H 2 * H + H + hνKinetic Energy of H atoms =ContinuumTherefore hν can be:Continuumb. Ar, Xe, HgUV-Vis-Near IRHeavy (High-Z) atoms Many atomic states+High Pressure (extensive broadening of lines)Quasi-ContinuumPage 91 of 316
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This came out a bit tedious again.C
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Full set of Notes with Fill-Ins - San Jose State University

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