Full set of Notes with Fill-Ins - San Jose State University

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Chem 155 Unit 10 Page 186 of 316Deviations due to Shifting Equilibria:For many molecules, especially weak acids, only one of theconjugate acid / base pair may absorb at a givenwavelength.This is how acid-base indicators work!Suppose only the conjugate base of a weak acid is colored.(think phenolphthalein!) What would a Beer’s law plot of anindicator like phenolphthalein (HA) in pure water look like?HA ⇔ H + + A -1. K EQ = [H + ][A - ] / [HA]absorbingGod, please just dump this one, please!Vastly simplify or dump.Concentration of HA insolution, theundissociated fraction.2. Conservation of mass: [HA 0 ] = [HA] + [A - ]so: [HA] = [HA 0 ] – [A - ]Number of moles of HA4. [A - ] = [H + ] (if >> 10 -7 M) divided by volume of insolution. Total or formalconcentration.5 = 1 + 4 K EQ = [A - ][A - ] / [HA]6 = 5 + 2 K EQ = [A - ] 2 / [HA 0 ] – [A - ]Page 186 of 316
Chem 155 Unit 10 Page 187 of 316K EQ = [A - ] 2 / [HA 0 ] – [A - ]try to solve for [A - ]…[A - ] 2 + K EQ [A - ] – K EQ [HA 0 ] = 0ax ⋅2+ bx ⋅ + c 0 x:=( )−b+ b 2 − 4a ⋅ ⋅c2a ⋅a = 1b = K EQc = K EQ [HA 0 ][A - ] =x( K , HAo):=−K+ K 2 + 4K ⋅ ⋅HAo2Page 187 of 316
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Full set of Notes with Fill-Ins - San Jose State University

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