Full set of Notes with Fill-Ins - San Jose State University

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Chem 155 Unit 13 Page 242 of 316Group frequencies: a pleasant fiction!Most molecules have many atoms.That means many modes! Some very complex!But –some functional groups behave like small molecules!Characteristic groupmodes and show up inIR spectra.Examples of ‘groups’:• C-H• C=O• C≡N• NH 3• OH etc.3N-6 rule irrelevant tothis analysisν is somewhatvariable because:• environment• other bonds• other modesinfluence the groupvibration.Page 242 of 316
Chem 155 Unit 13 Page 243 of 316p. 136 of Spectrometric Identification of Organic MoleculesR.M. Silverstein, F.M. Webster, Wiley 1998Page 243 of 316
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