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Advances in Water Treatment and Enviromental Management

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176 WATER TREATMENTIn this prelim<strong>in</strong>ary approach, we are especially <strong>in</strong>terested <strong>in</strong> the aggregation of a large numberof solid particles from a suspension on a filter surface, encountered <strong>in</strong> cross-flow ultrafiltrationconditions. Assum<strong>in</strong>g a low concentration of particles <strong>in</strong> the fluid, we consider that thoseparticles, driven by the flow, appear one by one near the wall. We will suppose the particles tobe spherical <strong>and</strong> monodispersed.Trajectories of such s<strong>in</strong>gle particles flow<strong>in</strong>g <strong>in</strong> the wall region have been precedently determ<strong>in</strong>edby Schmitz et al(1989). tak<strong>in</strong>g <strong>in</strong>to account hydrodynamical <strong>and</strong> physico-chemical forces. Ithas been shown that, <strong>in</strong> a first order approximation, such trajectories can be consideredl<strong>in</strong>ear, hav<strong>in</strong>g an <strong>in</strong>cidence angle with the horizontal porous plane surface.Hydrodynamical conditions, physico-chemical <strong>and</strong> double layer forces, brownian motion,concentration, density <strong>and</strong> particles shape effects are globally considered <strong>in</strong> a statisticalsimulation program which is able to perform <strong>and</strong> furthermore to visualize the deposition ofmicronic particles on a flat porous plate.3.1 Statistical ModelIn a rectangular 2D doma<strong>in</strong>, we <strong>in</strong>ject solid circular particles, one by one, follow<strong>in</strong>g l<strong>in</strong>eartrajectories from a r<strong>and</strong>om <strong>in</strong>itial location far from the wall. They move towards the filter surfacerepresented by a flat plate with rectangular holes. Special mov<strong>in</strong>g <strong>and</strong> stick<strong>in</strong>g rules are proposedto def<strong>in</strong>e the behaviour of particles <strong>in</strong> the flow <strong>and</strong> when they make contact with the filter orwith another particle already stick<strong>in</strong>g to the wall. Those empirical rules are given to characterizethe respective importance of the different phenomena which occur <strong>in</strong> the filtration zone.Fig. 3: Particle-particle adhesion rulesAdhesion rulesA particle of center A is immediately stopped when it makes contact with the filter wall. Whenit touches a previously aggregated particle of center B, it is also captured provided that thecenterl<strong>in</strong>e (AB) is <strong>in</strong>side the circular sector def<strong>in</strong>ed by the stick<strong>in</strong>g angle 6 as shown <strong>in</strong> Fig. 3.We then obta<strong>in</strong> two parameters θ i <strong>and</strong> θ v which determ<strong>in</strong>e respectively adhesion <strong>in</strong> <strong>in</strong>cident<strong>and</strong> vertical directions.Displacement rulesA l<strong>in</strong>ear <strong>in</strong>cident way is given to each particle A launched from its <strong>in</strong>itial po<strong>in</strong>t, characterizedby the <strong>in</strong>cidence angle a, another parameter of the model. After mak<strong>in</strong>g contact with a particleof center B, it turns left or right around this particle until reach<strong>in</strong>g a vertical or a new <strong>in</strong>cidenttrajectory <strong>and</strong> so on. The type of this new direction followed depends on the number ofreentra<strong>in</strong>ment permitted. The number of reentra<strong>in</strong>ments is a parameter which can be choosenfreely <strong>and</strong> accounts for the maximum number of possible “contacts” before a particle is f<strong>in</strong>allycaptured. The different cases which occurs are detailed <strong>in</strong> Fig. 4.Filter surfaceThe geometrical characteristics of the filter are taken <strong>in</strong>to account by the porosity parameter P<strong>and</strong> by the diameter ratio R d def<strong>in</strong><strong>in</strong>g the pore size over the particle size. Of course, particles arenot always captured as they can pass the filter if their diameter is smaller than the pore diameter.A realistic deposit on a porous surface is obta<strong>in</strong>ed when a multitude of particles move one byone from their <strong>in</strong>itial location to the dynamical collector composed of the filter <strong>and</strong> the previouslycaptured particles. In this dynamical simulation, the trajectory <strong>in</strong>cidence represents suction<strong>in</strong>tensity over parallel flow. The magnitudes of the two stick<strong>in</strong>g angles θ i <strong>and</strong> θ v characterizethe respective importance of perpendicular attractive forces compared to parallelhydrodynamical <strong>and</strong> perpendicular repulsive forces. The number of reentra<strong>in</strong>ments enhances

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