Advances in Water Treatment and Enviromental Management
Advances in Water Treatment and Enviromental Management
Advances in Water Treatment and Enviromental Management
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18 WATER TREATMENTTable 1: Comparison of regulations <strong>in</strong> US <strong>and</strong> <strong>in</strong> Europe.Some examples of differencies <strong>in</strong> MCLquality determ<strong>in</strong>ation by nitrates, seen as nationwide problem. On a local scale, however,th<strong>in</strong>gs may work out differently. Some sources, such as these generated by household effluentscan reach quite large proportions compared with farm<strong>in</strong>g activities. However, remedial solutionscan be found to alleviate this k<strong>in</strong>d of pollution.The situation when it comes to agricultural pollution is quite another matter. Its ma<strong>in</strong>characteristic is its wide diffusion mak<strong>in</strong>g the struggle to protect the quality of water highlycomplex.A dozen or so sound<strong>in</strong>g were carried out on the entire depth of the ground between the topsoil <strong>and</strong> the phreatic layer <strong>in</strong> different regions by the Geological <strong>and</strong> M<strong>in</strong><strong>in</strong>g Research Bureau<strong>in</strong> France (BRGM) (1). Their results br<strong>in</strong>g <strong>in</strong>terest<strong>in</strong>g elements:On all cultivated l<strong>and</strong> a stock of nitrates has been detected migrat<strong>in</strong>g towards the aquifers,<strong>and</strong> this without any noticeable attenuation of its concentration at <strong>in</strong>creas<strong>in</strong>g depths. Theseresults show that the possibilities of natural denitrification are limited. Just few cases ofdenitrification have been identified normaly <strong>in</strong> the chalk aquifer <strong>in</strong> northern France.The nitrate concentrations <strong>in</strong> <strong>in</strong>tersticial waters are rarely under 45 mg/1 <strong>and</strong> the projectcarried out <strong>in</strong> Brittany under market garden<strong>in</strong>g sites shows that the water conta<strong>in</strong>ed <strong>in</strong> thenon-saturated zone can reach a nitrate content <strong>in</strong> the region of 170 mg/1 with an average of130 mg/1.In <strong>in</strong>tensely cultivated areas, the total quantities of nitrogen <strong>in</strong>volved per annum are <strong>in</strong> theregion of 200 to 250 kg per hectare (Nitrogen of the soil plus extra <strong>in</strong>put from fertilizers). Itcan be assumed that the annual range of residual nitrates likely to be leached <strong>in</strong>to the subsoilis between 30 <strong>and</strong> 45 kg of nitrogen per hectare (15 % of the stock <strong>in</strong> soil). This leakageproduce concentrations <strong>in</strong> the aquifers of dose on 50 to 60 mg/1 of NO - 3 .This <strong>in</strong>dicates that <strong>in</strong> order to ma<strong>in</strong>ta<strong>in</strong> the quality of the groundwater, the farm<strong>in</strong>g practiceshould be able to reduce the leakage of nitrogen under 15 % of the total stock of nitrogenconta<strong>in</strong>ed <strong>in</strong> the soil. This is a difficult challenge.The orig<strong>in</strong> of the <strong>in</strong>crease <strong>in</strong> nitrate concentration doses not appear to be solely due to an<strong>in</strong>crease <strong>in</strong> the doses of nitrous fertilizers, but just as much to the changes <strong>in</strong> crop rotation<strong>and</strong> above all a great <strong>in</strong>crease <strong>in</strong> cropped areas. The draft Directive of the Council of the