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Advances in Water Treatment and Enviromental Management

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190 WATER TREATMENT<strong>in</strong> particular trihalomethanes, from water. The equilibrium isotherm for theadsorption of CHCl 3 onto silicalite is comparable with adsorption onto GAC, withthe considerable advantage for silicalite of simple regeneration by heat<strong>in</strong>g <strong>in</strong> air.Equilibrium data can be described over a broad range of THM concentrations bythe Freundlich isotherm. The constants <strong>in</strong> the isotherm are comparable with thosefor GAC.Rates of adsorption of chloroform from water by silicalite are comparable with thoseof GAC.ACKNOWLEDGEMENTSThis project is sponsored by the UK Science <strong>and</strong> Eng<strong>in</strong>eer<strong>in</strong>g Research Councilunder its Separation Processes Initiative <strong>and</strong> has the support<strong>in</strong>g <strong>in</strong>terest of the<strong>Water</strong> Research Centre, Stevenage. Also, the supply of Filtrasorb-400 activatedcarbon by Chemviron Carbon is gratefully acknowledged. The authors are alsoparticularly grateful to the staff of Wessex <strong>Water</strong> for their helpful advice <strong>in</strong>establish<strong>in</strong>g the analytical procedure used <strong>in</strong> this research programme.REFERENCESFaust, S D <strong>and</strong> Aly, O M (1987), Adsorption Processes for <strong>Water</strong> <strong>Treatment</strong>,Butterworths, BostonFlanigen, E M <strong>and</strong> Grose, R W (1977), US Patent 4,061, 724, December 6 1977Lange, N A (ed) (1985), Lange’s H<strong>and</strong>book of Chemistry, 13th Edn, McGraw-Hill,New YorkO’Brien, R P, Rizzo, J L, Schuliger, W G (1983), Removal of Organic Compoundsfrom Industrial Wastewaters Us<strong>in</strong>g Granular Carbon Column Processes, <strong>in</strong> B BBerger (ed) Control of Organic Substances <strong>in</strong> <strong>Water</strong> <strong>and</strong> Wastewater, EPA-600/8–83–011, pp337–362Ram, N M, Calabrese, E J, Christman, R F (1986), Organic Carc<strong>in</strong>ogens <strong>in</strong> Dr<strong>in</strong>k<strong>in</strong>g<strong>Water</strong>, Wiley, New York, p4Rook, J J (1974), <strong>Water</strong> Treat Exam, 23, 234Schultz-Sibbel, G M W, Gjerde, D T, Chriswell, C D <strong>and</strong> Fritz, J S (1982), Talanta,29, 447–452

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