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vgbe energy journal 7 (2022) - International Journal for Generation and Storage of Electricity and Heat

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Emission footprint analysis <strong>of</strong> dispatchable gas-based power generation technologies<br />

1 Legislation overview<br />

1.1 Utilization <strong>of</strong> g/kWh el as an<br />

apples-to-apples metric <strong>for</strong><br />

environmental footprint<br />

analyses<br />

Regulations <strong>and</strong> scientific publications commonly<br />

employ ppmvd 1 , mg/m N 3 , <strong>and</strong> also<br />

non-SI units as metrics <strong>for</strong> quantifying emissions<br />

from dispatchable gas-based power<br />

generation technologies. Emission values<br />

are typically normalized to a reference oxygen<br />

content to account <strong>for</strong> dilution <strong>of</strong> pollutants<br />

due to excess air <strong>and</strong> varying oxygen<br />

contents in the exhaust gas. In most cases,<br />

emissions from GT <strong>and</strong> RICE are normalized<br />

to different oxygen contents 2 . As a result,<br />

normalized emission values cannot be compared<br />

directly. Furthermore, even when the<br />

same reference oxygen content is utilized,<br />

emissions reported in ppmvd or mg/m N ³ do<br />

not account <strong>for</strong> power generation efficiency<br />

associated with the emission release. The<br />

present study uses g/kWh el as an apples-toapples<br />

metric <strong>for</strong> GT <strong>and</strong> RICE emissions to<br />

overcome these limitations. On the one<br />

h<strong>and</strong>, this metric accounts <strong>for</strong> the massbased<br />

emission release, which is essential <strong>for</strong><br />

environmental impact considerations. On<br />

the other h<strong>and</strong>, it considers the electrical efficiency<br />

<strong>of</strong> the investigated power generation<br />

technology, which is a primary indicator <strong>for</strong><br />

a comprehensive technology comparison.<br />

1.2 Comparison <strong>of</strong> major regulatory<br />

frameworks <strong>of</strong> GT <strong>and</strong> RICE<br />

As they impose binding constraints on power<br />

plant operators, regulations have an important<br />

impact on the emission footprint <strong>of</strong><br />

gas-based power generation technologies.<br />

However, significant variations in scope <strong>and</strong><br />

strictness can be observed when considering<br />

1<br />

ppmvd: parts per million by volume (dry)<br />

2<br />

For example, the German 13 th BImSchV defines<br />

a reference oxygen content <strong>of</strong> 15 vol.% <strong>for</strong><br />

GT <strong>and</strong> a reference oxygen content <strong>of</strong> 5 vol.%<br />

<strong>for</strong> RICE [3].<br />

3<br />

Environmental, Health <strong>and</strong> Safety Guidelines<br />

– Small Combustion Facilities Emission Guidelines<br />

[5]<br />

4<br />

Best available techniques (BAT) conclusions<br />

<strong>for</strong> large combustion plants [4]<br />

5<br />

Directive on the limitation <strong>of</strong> emissions from<br />

certain pollutants into the air from medium<br />

combustion plants (EMCP) [6]<br />

6<br />

Verordnung über Großfeuerungs-, Gasturbinen-<br />

und Verbrennungsmotoranlagen (13.<br />

BImSchV) [3]<br />

7<br />

Verordnung über mittelgroße Feuerungs- Gasturbinen-<br />

und Verbrennungsmotoranlagen<br />

(44. BImSchV) [7]<br />

8<br />

Exemplary Environmental Protection Agency<br />

(EPA) site permit [8]<br />

9<br />

The EU BAT conclusions specify value ranges<br />

instead <strong>of</strong> fixed emission limits. There<strong>for</strong>e,<br />

F i g u r e 1 considers the upper <strong>and</strong> lower<br />

bound <strong>of</strong> the respective NO X value ranges<br />

(BAT low <strong>and</strong> high).<br />

kWh el<br />

NO X emissions<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

GT-SC<br />

RICE-SC<br />

GT-CC<br />

RICE-CC<br />

0<br />

30 35 40 45 50 55 60 65 70<br />

el in %<br />

Fig.1. Emission limits <strong>of</strong> major current NO X regulations <strong>for</strong> GT <strong>and</strong> RICE.<br />

kWh el<br />

CO emissions<br />

1000<br />

900<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

GT-SC<br />

RICE-SC<br />

GT-CC<br />

RICE-CC<br />

13 th BImSchV<br />

WorldBank<br />

BAT low<br />

BAT high<br />

EPA (exemplary)<br />

EMCP<br />

44 th BImSchV<br />

13.BImSchV<br />

BAT low<br />

BAT high<br />

EPA (exemplary)<br />

44. BImSchV<br />

0<br />

30 35 40 45 50 55 60 65 70<br />

el in %<br />

Fig.2. Emission limits <strong>of</strong> the major current CO regulation <strong>for</strong> GT <strong>and</strong> RICE.<br />

current emission regulations <strong>for</strong> GT <strong>and</strong><br />

RICE from a national to a global level. To account<br />

<strong>for</strong> this variety, the present study examines<br />

emission guidelines issued by the<br />

World Bank 3 (WB), emission limits provided<br />

by the EU 4,5 <strong>and</strong> emission limits defined by<br />

national regulators in Germany 6,7 <strong>and</strong> the<br />

United States 8 . Employing the previously introduced<br />

metric <strong>of</strong> g/kWh el , Figure 1<br />

shows an apples-to-apples comparison between<br />

these regulations focusing on nitrogen<br />

oxides (generally referred to as NO X )<br />

emissions 9 depending on the net electrical<br />

efficiency <strong>of</strong> the generating unit.<br />

As most investigated regulations define<br />

emission limits in ppmvd or mg/m N ³, the<br />

conversion to g/kWh el requires in<strong>for</strong>mation<br />

regarding electrical efficiency. Differentiating<br />

between single cycle (SC) <strong>and</strong> combined<br />

cycle (CC) configurations, F i g u r e 1 accounts<br />

<strong>for</strong> a range <strong>of</strong> efficiency values associated<br />

with state-<strong>of</strong>-the-art GT <strong>and</strong> RICE 10 .<br />

For RICE, even though the legislation does<br />

not distinguish between SC <strong>and</strong> CC, the two<br />

technologies are colored differently due to<br />

their different electrical efficiencies. The<br />

displayed data indicate that the more strict<br />

regulations (i.e., EU BAT conclusions,<br />

13 th BImSchV, an exemplary EPA permit <strong>for</strong><br />

gas turbines) result in comparable emission<br />

limits in mass per generated <strong>energy</strong> output<br />

<strong>for</strong> SC-GT <strong>and</strong> SC-RICE. In contrast, the<br />

10<br />

For a given emission limit defined in ppmvd or<br />

mg/m N ³, an increase in electrical efficiency<br />

results in a decreased value in g/kWh el .<br />

Above certain efficiency thresholds <strong>for</strong> SC<strong>and</strong><br />

CC-GT configurations, the 13 th BImSchV<br />

<strong>and</strong> the EU BAT conclusions stipulate a linear<br />

increase in emission limits depending on the<br />

electrical efficiency. As a result, F i g u r e 1<br />

<strong>and</strong> F i g u r e 2 show constant emission limits<br />

when these efficiency limits are surpassed.<br />

<strong>vgbe</strong> <strong>energy</strong> <strong>journal</strong> 7 · <strong>2022</strong> | 33

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