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McKay, Donald. "Front matter" Multimedia Environmental Models ...

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give the derived units directly with no conversion factors. For example, energy<br />

(joules) is variously the product of force (newtons) and distance (metres), or pressure<br />

(pascals) and volume (cubic metres), or power (watts) and time (seconds). Thus, the<br />

foot-pound, the litre-atmosphere, and the kilowatt-hour become obsolete in favor of<br />

the single joule. Some key aspects of the SI system are discussed below. Conversion<br />

tables from obsolete or obsolescent unit systems are available in scientific handbooks.<br />

Length (metre, m)<br />

This base unit is defined as the specified number of wavelengths of a krypton<br />

light emission.<br />

Area<br />

Square metre (m 2 ). Occasionally, the hectare (ha) (an area 100 ¥ 100 m or 10 4 m 2 )<br />

or the square kilometre (km 2 ) is used. For example, pesticide dosages to soils are<br />

often given in kg/ha.<br />

Volume (cubic metre, m 3 )<br />

The litre (L) (0.001 m 3 ) is also used because of its convenience in analysis, but<br />

it should be avoided in environmental calculations. In the United States, the spellings<br />

“meter” and “liter” are often used.<br />

Mass (kilogram, kg)<br />

Kilogram (kg). The base unit is the kilogram (kg), but it is often more convenient<br />

to use the gram (g), especially for concentrations. For large masses, the megagram<br />

(Mg) or the equivalent metric tonne (t) may be used.<br />

Amount (mole abbreviated to mol)<br />

This unit, which is of fundamental importance in environmental chemistry, is<br />

really a number of constituent entities or particles such as atoms, ions, or molecules.<br />

It is the actual number of particles divided by Avogadro’s number (6.0 ¥ 10 23 ),<br />

which is defined as the number of atoms in 12 g of the carbon-12 isotope. When<br />

reactions occur, the amounts of substances reacting and forming are best expressed<br />

in moles rather than mass, since atoms or molecules combine in simple stoichiometric<br />

ratios. The need to involve atomic or molecular masses is thus avoided.<br />

Molar Mass or Molecular Mass (or Weight) (g/mol)<br />

This is the mass of 1 mole of matter and is sometimes (wrongly) referred to as<br />

molecular weight or molecular mass. Strictly, the correct unit is kg/mol, but it is<br />

often more convenient to use g/mol, which is obtained by adding the atomic masses<br />

(weights). Benzene (C6H6) is thus approximately 78 g/mol or 0.078 kg/mol.<br />

©2001 CRC Press LLC

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