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McKay, Donald. "Front matter" Multimedia Environmental Models ...

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Users are encouraged to modify the various parameter values and are cautioned<br />

that the values given are not necessary widely applicable. It should be noted again<br />

that varying the input temperature will not vary physical chemical properties such<br />

as vapor pressure. Temperature dependence must be entered “by hand.”<br />

8.5.1 Introduction<br />

©2001 CRC Press LLC<br />

8.5 A SEDIMENT-WATER EXCHANGE MODEL<br />

Exchange of chemical at the sediment-water interface can be important for the<br />

estimation of (1) the rates of accumulation or release from sediments, (2) the<br />

concentration of chemicals in organisms living in, or feeding from, the benthic<br />

region, (3) which transfer processes are most important in a given situation, and (4)<br />

the likely recovery times in the case of “in-place” sediment contamination. The<br />

complexity of the system and the varying properties of chemicals of possible concern<br />

lead to a situation in which a specific chemical’s behavior is not necessarily obvious.<br />

This situation treated here, and the resulting model are largely based on a<br />

discussion of sediment-water exchange by Reuber et al. (1987), Eisenreich (1987),<br />

Diamond et al. (1990), and in part on a report by Formica et al. (1988). It is depicted<br />

in Figure 8.3.<br />

Figure 8.3 Sediment-water exchange processes.

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