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HEMISKI Zbirka re{eni zada~i REAKTORI 3

HEMISKI Zbirka re{eni zada~i REAKTORI 3

HEMISKI Zbirka re{eni zada~i REAKTORI 3

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Zada~a 15<br />

T<strong>re</strong>t del. Proto~en <strong>re</strong>aktor od <strong>re</strong>zervoarski tip<br />

so idealno me{awe (CSTR). Polu{ar`en <strong>re</strong>aktor<br />

Esterifikacija na ocetna kiselina vo polu{ar`en <strong>re</strong>aktor<br />

Esterifikacija na ocetna kiselina so etilalkohol se<br />

izveduva vo polu{ar`en <strong>re</strong>aktor na 100 o C. 160 kg ~ist etanol<br />

(MA = 46, A = 0,785 kg/dm 3 ) e dodaden {ar`no vo <strong>re</strong>aktorot,<br />

dodeka 50%-en (mas<strong>eni</strong> %) voden rastvor na ocetna kiselina<br />

(MB = 60, rastvor = 1,0 kg/dm 3 ) se dodava kontinuirano so protok<br />

od 1,86 kg/min. Reakcijata e <strong>re</strong>verzibilna i elementarna:<br />

CH3COOH + C2H5OH CH3COOC2H5 + H2O<br />

B + A E + W<br />

so slednive v<strong>re</strong>dnosti na brzinskite konstanti:<br />

4<br />

3<br />

k 1 4,<br />

76 10<br />

(dm /mol)/min, k1<br />

1,<br />

6310<br />

(dm /mol)/min.<br />

Da se izvedat i grafi~ki da se prika`at v<strong>re</strong>menskite<br />

prom<strong>eni</strong> na koncentraciite na u~esnicite vo <strong>re</strong>akcijata i brzinata<br />

na <strong>re</strong>akcijata.<br />

Koe e racionalnoto v<strong>re</strong>me na rabota na <strong>re</strong>aktorot?<br />

Re{<strong>eni</strong>e:<br />

Ravenkite na molskite bilansi {to ja opi{uvaat rabotata<br />

vo polu{ar`en <strong>re</strong>aktor, za <strong>re</strong>akcijata A + B C, se ravenkite<br />

(86):<br />

dC A oC<br />

A<br />

rA<br />

<br />

dt V (t)<br />

dt<br />

o<br />

( CBo<br />

C<br />

<br />

V ( t)<br />

dCB B<br />

rB<br />

dt<br />

)<br />

4<br />

oC<br />

rC<br />

<br />

(86)<br />

V (t)<br />

dCC C<br />

V V ( t)<br />

Vo<br />

ot<br />

X<br />

A<br />

A<br />

C<br />

X ( t)<br />

<br />

B<br />

Ao<br />

V<br />

C<br />

o<br />

C<br />

C V ( t)<br />

Ao<br />

V<br />

(<br />

r ) ( r<br />

) r kC<br />

o<br />

A<br />

A<br />

C<br />

B<br />

3<br />

193

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