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HEMISKI Zbirka re{eni zada~i REAKTORI 3

HEMISKI Zbirka re{eni zada~i REAKTORI 3

HEMISKI Zbirka re{eni zada~i REAKTORI 3

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Re{<strong>eni</strong>e:<br />

Reaktorot e so daden volumen (p<strong>re</strong>ku volumenskoto v<strong>re</strong>me)<br />

i raboti adijabatski. Zna~i, za <strong>re</strong>{avawe na zada~ata se pot<strong>re</strong>bni<br />

ravenkata za dizajn na PFR i toplinskiot bilans za adijabatska<br />

rabota na <strong>re</strong>aktorot. No najnap<strong>re</strong>d podgotovkata na brzinskiot<br />

izraz,<br />

CB<br />

( rA<br />

) k(<br />

T)<br />

( C A ) , (1)<br />

K(<br />

T)<br />

p<strong>re</strong>ku konverzija, odnosno izrazuvawe na molskite koncentracii<br />

p<strong>re</strong>ku konverzija. Za toa ne e pot<strong>re</strong>bno da se formira stehiometriska<br />

tablica, bidej}i vkupniot borj molovi so <strong>re</strong>akcijata<br />

ne se menuva, a stehiometrijata e ednostavna. No, ako <strong>re</strong>akcijata<br />

e vo gasna faza i se odviva vo neizotermni uslovi, toga{<br />

volumenskiot protok }e se menuva so temperaturata. Zatoa za<br />

molskite koncentracii }e gi imame slednive izrazi:<br />

248<br />

C<br />

C<br />

A<br />

B<br />

FA<br />

( X ) FAo<br />

( 1<br />

X )<br />

<br />

C<br />

(<br />

T)<br />

( T / T )<br />

FB<br />

( X ) FAo<br />

X<br />

C<br />

(<br />

T ) ( T / T )<br />

o<br />

o<br />

o<br />

o<br />

Ao<br />

Ao<br />

To<br />

( 1<br />

X ) ,<br />

T<br />

To<br />

X .<br />

T<br />

Iako vo ovaa zada~a se p<strong>re</strong>smetuva adijabatska rabota na<br />

<strong>re</strong>aktorot, za odnosot To/T vo izrazite (2) mo`e da se zeme deka<br />

nema bitno vlijanie, odnosno deka e To/T = 1,0 (podocna ovaa<br />

p<strong>re</strong>tpostavka }e se poka`e opravdana). So ovaa p<strong>re</strong>tpostavka<br />

izrazite za molskite koncentracii se:<br />

C ( 1<br />

X ) ; C C C C X . (3)<br />

C A Ao<br />

B Ao A Ao<br />

Temperaturnata zavisnost na brzinskata konstanta e<br />

dadena, dodeka za ramnote`nata t<strong>re</strong>ba da se od<strong>re</strong>di:<br />

8 8<br />

1<br />

k ( T)<br />

5 10<br />

exp( 50000/(<br />

R T<br />

)) 5 10<br />

exp( 6014<br />

/ T)<br />

( h ) , (4)<br />

<br />

H<br />

K(<br />

T ) K 298K<br />

exp<br />

R<br />

r<br />

1<br />

<br />

T<br />

1 <br />

70000 1 1 <br />

<br />

20exp<br />

<br />

298<br />

<br />

<br />

8,<br />

3144 T 298 <br />

(2)<br />

( T 298)<br />

<br />

K(<br />

T ) 20exp<br />

<br />

28,<br />

252<br />

<br />

. (5)<br />

<br />

T

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