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Rotational Raman scattering in the Earth's atmosphere ... - SRON

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26 Chapter 2<br />

Figure 2.2: Fill<strong>in</strong>g-<strong>in</strong> for a model layer with ω ray = 1 and τ = 0.4 which is irradiated by a syn<strong>the</strong>tic<br />

solar spectrum with <strong>the</strong> Fraunhofer l<strong>in</strong>e <strong>in</strong> Eq. (2.20). The upper panel shows <strong>the</strong> fill<strong>in</strong>g-<strong>in</strong> f ref versus<br />

wavelength λ for a fixed optimized wavenumber grid with n max = 3 and ǫ = 10 −6 . Below is <strong>the</strong><br />

difference with f ref versus threshold ǫ at <strong>the</strong> l<strong>in</strong>e center at λ = 393.48 nm (left) and at <strong>the</strong> cont<strong>in</strong>uum at<br />

λ = 398.18 nm (right) for n max = 1, 2, 3. For a threshold of ǫ = 10 −2 only <strong>the</strong> Cabannes l<strong>in</strong>e is selected,<br />

which results <strong>in</strong> f −f ref = −17.25% at <strong>the</strong> l<strong>in</strong>e center (falls outside range). All calculations were done<br />

for a fixed geometry with solar zenith angle ϑ 0 = 60 ◦ , view<strong>in</strong>g angle ϑ v = 30 ◦ and azimuthal angle<br />

difference ϕ v −ϕ 0 = 10 ◦ . Four Gaussian quadrature po<strong>in</strong>ts were used to describe <strong>the</strong> <strong>in</strong>ternal radiation<br />

field. Fur<strong>the</strong>rmore, a Gaussian <strong>in</strong>strument function with a full width at half maximum of 0.2 nm was<br />

applied to simulate GOME-type measurements.

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